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Crystal Structure and Characterization of a New Eight Coordinated Cadmium Complex
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 Title & Authors
Crystal Structure and Characterization of a New Eight Coordinated Cadmium Complex
Hakimi, Mohammad; Moeini, Keyvan; Mardani, Zahra; Khorrami, Farzaneh;
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 Abstract
In this work, a new cadmium complex (1) with the ligand L, N,N'-bis(2-pyridinecarboxalidene)-1,2-cyclohexanediamine was prepared and identified by elemental analysis, FT-IR, Raman, NMR spectroscopy and single-crystal X-ray diffraction. The cadmium atom in the crystal structure of 1 has distorted triangular dodecahedral geometry by coordination of the four nitrogen atoms of L and four oxygen atoms of the two acetate ions. Two water molecules are also incorporated in the crystal network. The hydrogen bonds present in the crystal structure of 1. In this work, three structural surveys including coordination numbers of the cadmium atom, coordination modes of L and resonance in pyridine-2-ylmethanimine-based compounds are presented.
 Keywords
Triangulated dodecahedral geometry;Cadmium complex;Spectral characterization;X-ray crystal structure;
 Language
English
 Cited by
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