Rate Enhancement by Micelle Encapsulation for Oxidation of L-Glutamic Acid in Aqueous Media at Room Temperature

Mukherjee, Kakali; Saha, Bidyut

doi:10.5012/jkcs.2013.57.4.425

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Rate Enhancement by Micelle Encapsulation for Oxidation of L-Glutamic Acid in Aqueous Media at Room Temperature

Journal title : Journal of the Korean Chemical Society
Volume 57, Issue 4, 2013, pp.425-431
Publisher : Korean Chemical Society
DOI : 10.5012/jkcs.2013.57.4.425

Title & Authors

Rate Enhancement by Micelle Encapsulation for Oxidation of L-Glutamic Acid in Aqueous Media at Room Temperature
Mukherjee, Kakali; Saha, Bidyut;

Abstract

Oxidation of glutamic acid is performed in aqueous acid media at ${$30^{\circ}C$}$ under the kinetic condition [glutamic acid] ${$_T{\gg}[Cr(VI)]_T$}$ . Effect of combination of micellar catalyst (SDS, TX-100) and promoter (PA, bpy, phen) has been studied. Among the promoters phen accelerates the reaction most in aqueous media. But the rate acceleration is small in the case. Combination of promoter and catalyst produces much better result. Maximum rate enhancement occurs in presence of the combination of bpy and SDS.

Keywords

Oxidation;Micelle;Catalyst;Promoter;

Language

English

Cited by

1time(s) in CrossRef

Micellar catalyzed hydrolysis of mono-2,3-dichloroaniline phosphate, Journal of Dispersion Science and Technology, 2017

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