JOURNAL BROWSE
Search
Advanced SearchSearch Tips
Spectral and Geometrical Study of Two Cadmium Complexes, mer-R,S-[Cd(aepn)2]X2 (X: I-, Cl-, aepn: N-(2-Aminoethyl)-1,3-propanediamine) Supported by Solution Experiments
facebook(new window)  Pirnt(new window) E-mail(new window) Excel Download
 Title & Authors
Spectral and Geometrical Study of Two Cadmium Complexes, mer-R,S-[Cd(aepn)2]X2 (X: I-, Cl-, aepn: N-(2-Aminoethyl)-1,3-propanediamine) Supported by Solution Experiments
Hakimi, Mohammad; Mardani, Zahra; Moeini, Keyvan;
  PDF(new window)
 Abstract
In this research, two new complexes of N-(2-aminoethyl)-1,3-propanediamine (aepn), (1) and (2), were prepared and identified by elemental analysis, FT-IR, Raman spectroscopy and single-crystal X-ray diffraction. Geometry around the cadmium atom in two complexes by coordination of six nitrogen atoms of two aepn is distorted octahedral. If distortion in the mer- cation is disregarded, it has a axis and symmetry. The cyclic voltammetry experiments were carried out to study the complexation process. Two structural surveys on coordination modes and complexes of aepn are presented. A study was carried out using CSD data to estimate the averages of bond lengths for different types of the Cd-N bonds. It was found that the intermolecular , hydrogen bonds in 1 and , , , in 2 stabilized the crystal networks.
 Keywords
Cadmium complex;Chiral center;Diastereomer;Cyclic voltammetry;X-ray crystal structure;
 Language
English
 Cited by
1.
Structural and Spectral Characterization of a Chromium(III) Picolinate Complex: Introducing a New Redox Reaction,;

대한화학회지, 2013. vol.57. 6, pp.721-725 crossref(new window)
1.
Coordination behavior of dimethyl pyridine-2,6-dicarboxylate towards mercury(II), cadmium(II) and chromium(III) in the solid- and gaseous state supported by CSD studies, Polyhedron, 2015, 102, 569  crossref(new windwow)
2.
Microwave-assisted template synthesis of diazacyclam-based macrocyclic copper complex and forming octahedral, square planar and square pyramidal geometries by ion exchanging and introducing a novel 2D square-grid copper–mercury coordination polymer, Polyhedron, 2014, 70, 92  crossref(new windwow)
3.
Structural and Spectral Characterization of a Chromium(III) Picolinate Complex: Introducing a New Redox Reaction, Journal of the Korean Chemical Society, 2013, 57, 6, 721  crossref(new windwow)
 References
1.
Bartoszak-Adamska, E.; Bregier-Jarzebowska, R.; Lomozik, L. Polyhedron 2002, 21, 739. crossref(new window)

2.
Cannas, M.; Marongiu, G.; Saba, G. J. Chem. Soc. Dalton Trans. 1980, 2090.

3.
Mondal, A.; Mostafa, G.; Ghosh, A.; Chaudhuri, N. R. J. Chem. Res. 1998, 570.

4.
Hakimi, M.; Mardani, Z.; Moeini, K.; Fernandes, M. A. J. Coord. Chem. 2012, 65, 2221. crossref(new window)

5.
Chun, H.; Maes, E. M.; Czernuszewicz, R. S.; Bernal, I. Polyhedron 2001, 20, 2597. crossref(new window)

6.
Hakimi, M.; Moeini, K.; Mardani, Z.; Schuh, S.; Mohr, F. J. Coord. Chem. 2013, 66, 1129. crossref(new window)

7.
Perera, T.; Marzilli, P. A.; Fronczek, F. R.; Marzilli, L. G. Inorg. Chem. 2010, 49, 5560. crossref(new window)

8.
Kratochvil, B.; Ondracek, J.; Ondrackova, J.; Soldanova, J.; Jursik, F.; Hajek, B. Collect. Czech. Chem. Commun. 1987, 52, 949. crossref(new window)

9.
House, D. A.; Browning, J.; Zipper, L.; Marty, W. Inorg. Chim. Acta 1999, 288, 181. crossref(new window)

10.
Paharova, J.; Cernak, J.; Zak, Z.; Marek, J. J. Mol. Struct. 2007, 842, 117. crossref(new window)

11.
Allen, F. H. Acta Crystallogr. 2002, B58, 380.

12.
Dolomanov, O. V.; Bourhis, L. J.; Gildea, R. J.; Howard, J. A. K.; Puschmann, H. J. Appl. Crystallogr. 2009, 42, 339. crossref(new window)

13.
Sheldrick, G. M. Acta Crystallogr. 2008, A64, 112.

14.
Derwahl, A.; Robinson, W. T.; House, D. A. Inorg. Chim. Acta 1996, 247, 19. crossref(new window)

15.
Ishii, M.; Sato, S.; Saito, Y.; Nakahara, M. Chem. Lett. 1981, 1613.

16.
Wen, R.; Somoza, F.; Bernal, I.; Fronczek, F. R. J. Coord. Chem. 1999, 48, 443. crossref(new window)

17.
Escuer, A.; Font-Bardia, M.; Penalba, E.; Solans, X.; Vicente, R. Inorg. Chim. Acta 1999, 286, 189. crossref(new window)

18.
Hakimi, M.; Maeder, M.; Lawrance, G. A. J. Coord. Chem 2011, 64, 105. crossref(new window)

19.
Hakimi, M.; Mardani, Z.; Moeini, K.; Mohr, F.; Schuh, E.; Vahedi, H. Z. Naturforsch. 2012, 67b, 452. crossref(new window)

20.
Hakimi, M.; Mardani, Z.; Moeini, K.; Minoura, M.; Raissi, H. Z. Naturforsch. 2011, 66b, 1122.

21.
Deveci, P.; Taner, B.; Klllç, Z.; Solak, A. O.; Arslan, U.; Ozcan, E. Polyhedron 2011, 30, 1726. crossref(new window)

22.
Lopez-Torres, E.; Mendiola, M. A. Polyhedron 2005, 24, 1435. crossref(new window)

23.
Feng, X.; Li, Z.-F.; Xue, S.-F.; Tao, Z.; Zhu, Q.-J.; Zhang, Y.-Q.; Liu, J.-X. Inorg. Chem. 2010, 49, 7638. crossref(new window)

24.
Martell, A. E.; Smith, R. M.; Motekaites, R. J. NIST Criticially Selected Stability Constants of Metal Complexes, V. 8.0; NIST: Gaithersburg, MD; 2004.

25.
Farrugia, L. J. J. Appl. Crystallogr. 1997, 30, 565.

26.
Bergerhoff, G.; Berndt, M.; Brandenburg, K. J. Res. Natl. Inst. Stand. Technol. 1996, 101, 221. crossref(new window)

27.
Hakimi, M.; Moeini, K.; Mardani, Z.; Fernandes, M. A.; Mohr, F.; Schuh, E. J. Coord. Chem. 2012, 65, 1232. crossref(new window)

28.
ConQuest 1.14, Cambridge Crystallographic Data Centre: Cambridge, U.K.; 2012.

29.
Antonova, E.; Nather, C.; Kogerler, P.; Bensch, W. Inorg. Chem. 2012, 51, 2311. crossref(new window)