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Synthesis, Characterization, DFT Modeling and Antimicrobial Studies on the Ti(IV), Y(III) and Ce(IV) Ofloxacin Solid Complexes
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 Title & Authors
Synthesis, Characterization, DFT Modeling and Antimicrobial Studies on the Ti(IV), Y(III) and Ce(IV) Ofloxacin Solid Complexes
Sadeek, Sadeek A.; Zordok, Wael A.; El-Shwiniy, Walaa H.;
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 Abstract
A new solid complexes of Ti(IV), Y(III) and Ce(IV) have been synthesized with ofloxacin. The formulae and structure of the complexes have been proposed in the light of analytical, spectral ( NMR, IR and UV-Visible), magnetic, molar conductivities and thermal studies. The complexes are soluble in DMSO- and DMF. The measured molar conductance values indicate that, the three complexes are electrolyte in nature. The results support the formation of the complexes and indicated that ofloxacin reacts as a bidentate ligand chelate to the metal ion through the pyridone oxygen and one carboxylato oxygen. The kinetic parameters of thermogravimetric and its differential have been evaluated by using Coats Redfern (CR) and Horowitz-Metzeger (HM) methods. The thermodynamic data reflect the thermal stability for all complexes. The metal- ligand binding of the Ti(IV), Y(III) and Ce(IV) complexes is predicted using density funcational theory at the B3LYP-CEP-31G level of theory and total energy, dipole moment estimation of different Ti(IV), Y(III) and Ce(IV) ofloxacin structures. The biological activities of the ofloxacin, inorganic salts and their metal complexes were assayed against different bacterial species.
 Keywords
HOfl;DFT; NMR;IR;
 Language
English
 Cited by
1.
Complex formation equilibria between aluminum(III), gadolinium(III) and yttrium(III) ions and some fluoroquinolone ligands. Potentiometric and spectroscopic study, Journal of Coordination Chemistry, 2015, 68, 24, 4272  crossref(new windwow)
 References
1.
Nelson, J. M.; Chiller, T. M.; Powers, J. H.; Angulo, F. J. Clin. Infect. Dis. 2007, 44, 977. crossref(new window)

2.
Kawahara, S. Nippon. Rinsho. 1998, 56, 3096.

3.
Aleixandre, V.; Herrera, G.; Urios, A.; Blanco, M. Antimicrob. Agents Chemother. 1991, 35, 20. crossref(new window)

4.
Chu, D. T. W.; Fernandes, P. B. in: B. Testa (Ed.) In Advances in Drug Research; Testa, B., Ed.; Acodemic Press: London, 1991, 21, 39-144. crossref(new window)

5.
Park, H. R.; Chung, K. Y.; Lee, H. C.; Lee, J.-K.; Bark, K.-M. Bull. Korean Chem. Soc. 2000, 21, 849.

6.
Kapetanovic, V.; Milovanovlc, L. J. Talanta 1996, 43, 2123. crossref(new window)

7.
Yoshida, A.; Moroi, R. Anal. Sci. 1991, 7, 351. crossref(new window)

8.
Macias, B.; Villa, M. V.; Sastre, M.; Castineras, A.; Borras, J. J. Pharm. Sci. 2002, 91, 2416. crossref(new window)

9.
Macias, B.; Villa, M. V.; Rubio, I.; Castineras, A.; Borras, J. J. Inorg. Biochem. 2001, 84, 163. crossref(new window)

10.
Drevensek, P.; Kosmrlj, J.; Giester, G.; Skauge, T., Sletten, E.; Sepcic, K.; Turel, I. J. Inorg. Biochem. 2006, 100, 1755. crossref(new window)

11.
Sagdinc, S.; Bayari, S. J. Mol. Struct. (Theochem) 2004, 668, 93. crossref(new window)

12.
Xu, M.; Ma, Z.-R.; Huang, L.; Chen, F.-J.; Zeng, Z.-Z. Spectrochim. Acta, Part A 2011, 78, 503. crossref(new window)

13.
Sagdinc, S.; Bayarl, S. J. Mol. Struct. 2005, 744-747, 369. crossref(new window)

14.
Li, Y.; Chai, Y.; Yuan, R.; Liang, W. Russ. J. Inorg. Chem. 2008, 53, 704. crossref(new window)

15.
Sagdinc, S.; Bayarl, S. J. Mol. Struct. 2004, 691, 107. crossref(new window)

16.
Zordok, W. A.; El-Shwiniy, W. H.; El-Attar, M. S.; Sadeek, S. A. J. Mol. Struct. 2013, 1047, 267. crossref(new window)

17.
Frisch, M. J.; et al. Gaussian 98, revision A.6; Gaussian Inc.: Pittsburgh, PA, 1998.

18.
Stevens, W. J.; Krauss, M.; Bosch, H.; Jasien, P. G. Can. J. Chem. 1992, 70, 612.

19.
Beecher, D. J.; Wong, A. C. Identification of Hemolysin Bl-Producing Bacillus Cereus Isolated by a Discontinuous Hemolytic Pattern in Blood Agar. Appl. Environ. Microbiol. 1994, 60, 1646.

20.
Rupini, B.; Mamatha, K.; Mogili, R.; Ravinder, M.; Srihari, S. J. Indian Chem. Soc. 2007, 84, 629.

21.
Efthimiadou, E. K.; Sanakis, Y.; Katsaros, N.; Karaliota, A.; Psomas, G. Polyhedron 2007, 26, 1148. crossref(new window)

22.
Efthimiadou, E. K.; Katsaros, N.; Karaliota, A.; Psomas, G. Bioorg. Med. Chem. Lett. 2007, 17, 1238. crossref(new window)

23.
Efthimiadou, E. K.; Psomas, G.; Sanakis, Y.; Katsaros, N.; Karaliota, A. J. Inorg. Biochem. 2007, 101, 525. crossref(new window)

24.
Nakamoto, K. Infrared and Raman Spectra of Inorganic and Coordination Compound, Part B; Wiley: New York, 1997.

25.
Roeges, P. G. A J. Chem. Educ. 1995, 72, A93.

26.
Ruiz, M.; Ortiz, R.; Perello, L. Inorg. Chim. Acta 1993, 211, 133. crossref(new window)

27.
Ruiz, M.; Perello, L.; Ortiz, R.; Castineiras, A.; Maichle-Mossmer, C.; Canton, E. J. Inorg. Biochem. 1995, 59, 801. crossref(new window)

28.
Moawad, M. M.; Hanna, W. G. J. Coord. Chem. 2002, 55, 439. crossref(new window)

29.
Ismail, T. M. A. J. Coord. Chem. 2005, 58, 141. crossref(new window)

30.
Ruiz, M.; Ortiz, R.; Perello, L. Inorg. Chim. Acta 1993, 211, 133. crossref(new window)

31.
Lever, A. B. P. Inorganic Electronic Spectroscopy; Elesvier: Amsterdam, 1984.

32.
Brzyska, W.; Hakim, M. Polish J. Chem. 1992, 66, 413.

33.
Tagawa, H. Thernochim. Acta 1984, 80, 23. crossref(new window)

34.
Coats, A. W.; Redfern, J. P. Nature 1964, 201, 68. crossref(new window)

35.
Horowitz, H. W.; Metzger, G. Anal. Chem. 1963, 35, 1464. crossref(new window)

36.
Nair, M. K. M.; Radhakrishnan, P. K. Thermochim. Acta 1995, 261, 141. crossref(new window)

37.
Frost, A. A.; Pearson, R. G. Kinetics and Mechanism-A study of Homogenous Chemical Reaction; Wiley: New York, 1961.

38.
Raman, N.; Kulandaisamy, A.; Jayasubramanion, K. Polish J. Chem. 2002, 76, 1085.

39.
Tweedy, B. G. Phytopathology 1964, 55, 910.

40.
Balhausen, C. J. An Introduction to ligand field; McGraw Hill: New York, 1962.

41.
Chohan, Z. H.; Scozzafava, A.; Supuran, C. T. J. Enzym. Inhib. Med. Chem. 2003, 17, 261.

42.
Chohan, Z. H. Appl. Organomet. Chem. 2002, 10, 17.

43.
Kohn, W.; Sham, L. J. Phys. Rev. A 1965, 140, 1133. crossref(new window)

44.
Becke, A. D. Phys. Rev. A 1988, 38, 3098. crossref(new window)

45.
Lee, C.; Yang, W.; Parr, R. G. Phys. Rev. B 1988, 37.

46.
Flurry Jr., R. L. Molecular Orbital Theory of Bonding in Organic Molecules; Marcel Dekker: New York, 1968.

47.
Hyper Chem 7.5 Release for Windows; Hypercube Inc.: USA, 2003.

48.
Turel, I.; Golic, L.; Bukovec, P.; Gubina, M. J. Inorg. Biochem. 1998, 71, 53. crossref(new window)

49.
Turel, I.; Leban, I.; Klintschar, G.; Bukovec, N.; Zalar, S. J. Inorg. Biochem. 1997, 66, 77. crossref(new window)

50.
Yang, Y.; Gao, H. Spectrochemica Acta, Part A 2012, 85, 303. crossref(new window)

51.
Andrews, P. C.; Beck, T.; Frasr, B. H.; Junk, P. C.; Massi, M. Polyhedron 2007, 26, 5406.

52.
Khoshnavazi, R.; Salimi, A.; A. Ghiasi-Moaser Polyhedron 2008, 27, 1303. crossref(new window)

53.
Chen, Q.; Chang, Y. D.; Zubieta, J. Inorganic. Chemica. Acta 1997, 258, 257. crossref(new window)

54.
Shen, L. L. In Quinolone Antimicrobial Agents, 2nd ed.; Hopper, D. C.; Wolfson, J. S.; Eds.; American Society for Microbiology: Washington, DC, 1993; p 77.

55.
Jacobsen, E. N.; Pfaltz, A.; Yamamoto, H. Comprehensive Asymmetric Catalysis, Vol. 1-3; Springer: Berlin, 1999.

56.
Noyori, R. Asymmetric Catalysis in Organic Synthesis; Wiley: New York, 1994.

57.
Davis, T. J.; Carroll, P. J. Walsh, P. J. J. Organomet. Chem. 2002, 663, 70. crossref(new window)

58.
Liu, Y. Y.; Ma, J. F.; Xie, Y. P. Acta Crystallogr. 2006, Sect. E E62, 3786.

59.
Garima Singh Baghel; Chebrolu P. Rao Polyhedron 2009, 28, 3507. crossref(new window)

60.
Turel, I.; Leban, I.; Gruber, K.; Bukovec, N. J. Inorg. Biochem. 1996, 61, 197. crossref(new window)

61.
Tjaden, E. B.; Swenson, D. C.; Jordan, R. F.; Petersen, J. L. Organomet. 1995, 14, 371. crossref(new window)

62.
Coles, S. J.; Hursthouse, M. B.; Kelly, D. G.; Toner, A. J.; Walker, N. M. J. Organomet. Chem. 1999, 580, 304. crossref(new window)

63.
Gao, H. L.; Yi, L.; Zhao, B.; Zhao, X. Q.; Cheng, P.; Liao, D. Z.; Yan, S. P. Inorg. Chem. 2006, 45, 5980. crossref(new window)

64.
Aghabozorg, H.; Motieiyan, E.; Salimi, A. R.; Mirzaei, M.; Manteghi, F.; Shokrollahi, A.; Derki, S.; Ghadermazi, M.; Sheshmani, S.; Eshtiagh-Hosseini, H. Polyhedron 2010, 29, 1453. crossref(new window)

65.
Hubert-Pfalzgraf, L. G. New J. Chem. 1995, 19, 727

66.
Hubert-Pfalzgraf, L. G.; Guillon, H. Appl. Organomet. Chem. 1998, 12, 321. crossref(new window)

67.
Pang, M.; Meng, G. Y.; Xin, H. W.; Chen, C. S.; Peng, D. K.; Lin, Y. S. Thin Solid Films 1998, 324, 89. crossref(new window)

68.
Daniele, S.; Hubert-Pfalzgraf, L. G.; Perrin, M. Polyhedron 2002, 21, 1985. crossref(new window)

69.
Asakura, K.; Imamoto, T. Bull. Chem. Soc. Jpn. 2001, 74, 731. crossref(new window)

70.
Berthet, J.-C.; Nierlich, M.; Ephritikhine, M. Polyhedron 2003, 22, 3475. crossref(new window)