Structural and Spectral Characterization of a Chromium(III) Picolinate Complex: Introducing a New Redox Reaction

Hakimi, Mohammad

doi:10.5012/jkcs.2013.57.6.721

Title & Authors

Structural and Spectral Characterization of a Chromium(III) Picolinate Complex: Introducing a New Redox Reaction
Hakimi, Mohammad;

Abstract

Reaction between 2-pyridinecarboxylic acid (Hpic) and ${$K_3[Cr(O_2)_4]$}$ give complex ${$[Cr(pic)_3].H_2O$}$ (1) which is characterized by elemental analysis and spectroscopic methods (FT-IR, Raman) and X-ray crystallography. In the crystal structure of 1, chromium atom with coordinated by three nitrogen and three oxygen atoms has a distorted octahedral geometry. Also a water molecule is incorporated in crystal network. Each water molecule acts as hydrogen bond bridging and connects two adjacent complexes by two ${$O-H{\cdots}O$}$ hydrogen bonds.

Keywords

Chromium(III) complex;Picolinate;Spectral characterization;X-ray crystal structure;

Language

English

Cited by

1time(s) in CrossRef

1.

Isonicotinic acid hydrazide-based silver nanoparticles as simple colorimetric sensor for the detection of Cr3+, Sensors and Actuators B: Chemical, 2015, 216, 402

References

1.

(a) Wachter, G. A.; Davis, M. C.; Martin, A. R.; Franzblau, S. G. J. Med. Chem. 1998, 41, 2436.

2.

(b) Jew, S.; et al. Bioorg. Med. Chem. Lett. 2003, 13, 609.

3.

Li, G.; Qian, X.; Cui, J.; Huang, Q.; Zhang, R.; Guan, H. J. Agric. Food. Chem. 2006, 54, 125.

4.

(a) Strearns, D. M.; Armstrong, W. H., Inorg. Chem. 1992, 31, 5178.

5.

(b) Gonzales-Vergara, E.; Hegenauer, J.; Saltman, P.; Sabat, M.; Ibers, J. A. Inorg. Chim. Acta 1982, 66, 115.

6.

(c) Grant-Mauk, A.; Coyle, C. L.; Bordignon, E.; Gray, H. B. J. Am. Chem. Soc. 1979, 101, 5054.

7.

(d) Libby, E.; Webb, R. J.; Streib, W. E.; Folting, K.; Huffman, J. C.; Hendrickson, D. N.; Christou, G., Inorg. Chem. 1989, 28, 4037.

8.

(e) Jfns, O.; Johansen, E. S., Inorg. Chim. Acta 1988, 151, 129.

9.

(f) Dixit, S. C.; Sharan, R.; Kapoor, R. N. Inorg. Chim. Acta 1989, 158, 109.

10.

(g) Li, W.; Olmstead, M. M.; Miggins, D.; Fish, R. H. Inorg. Chem. 1996, 35, 51.

11.

(a) Hakimi, M.; Mardani, Z.; Moeini, K.; Fernandes, M. A. J. Coord. Chem. 2012, 65, 2221.

12.

(b) Hakimi, M.; Mardani, Z.; Moeini, K.; Schuh, E.; Mohr, F. Z. Naturforsch. 2013, 68b, 272.

13.

(c) Hakimi, M.; Mardani, Z.; Moeini, K.; Schuh, E.; Mohr, F. Z. Naturforsch. 2013, 68b, 267.

14.

(d) Hakimi, M.; Moeini, K.; Mardani, Z.; Schuh, S.; Mohr, F. J. Coord. Chem. 2013, 66, 1129.

15.

(e) Hakimi, M.; Moeini, K.; Mardani, Z.; Khorrami, F. J. Korean Chem. Soc. 2013, 57, 352.

16.

(f) Hakimi, M.; Mardani, Z.; Moeini, K.; Mohr, F.; Fernandes, M. A. Polyhedron 2014, 67, 27.

17.

Nguyen, T.; Panda, A.; Olmstead, M. M.; Richards, A. F.; Stender, M.; Brynda, M.; Power, P. P. J. Am. Chem. Soc. 2005, 127, 8545.

18.

Groysman, S.; Villagran, D.; Nocera, D. G. Inorg. Chem. 2010, 49, 10759.

19.

Cotton, F. A.; Rice, C. E.; Rice, G. W. Inorg. Chim. Acta 1977, 24, 231.

20.

Monillas, W. H.; Yap, G. P. A.; Theopold, K. H. J. Chem. Cryst. 2011, 41, 415.

21.

Hakimi, M.; Kukovec, B.-M.; Minoura, M. J. Chem. Crystallogr. 2012, 42, 290.

22.

Dingwall, J. G.; Tuck, B. Angew. Chem. Int. Ed. Engl. 1983, 22, 498.

23.

Ganesan, M.; Gabbai, F. P. Organometallics 2004, 23, 4608.

24.

Koide, H.; Uemura, M. Tetrahedron Lett. 1999, 40, 3443.

25.

Barr, R. D.; Green, M.; Marsden, K.; Stone, F. G. A.; Woodward, P. J. Chem. Soc., Dalton Trans. 1983, 507.

26.

Braunstein, P.; Tiripicchio, A.; Tiripicchio-Camellini, M.; Sappa, E. Inorg. Chem. 1981, 20, 3586.

27.

Braga, D.; Eckert, M.; Fraccastoro, M.; Maini, L.; Grepi-oni, F.; Caneschi, A.; Sessoli, R. New J. Chem. 2002, 26, 1280.

28.

Aldridge, S.; Hashimoto, H.; Kawamura, K.; Shang, M.; Fehlner, T. P. Inorg. Chem. 1998, 37, 928.

29.

Sheldrick, G. M. SADABS: Program for Empirical Absorption Correction of Area Detector Data, University of Gottingen: Gottingen, Germany, 1996.

30.

Sheldrick, G. M. SHELXS/L-97: Program for Empirical Absorption Correction of Area Detector Data, University of Gottingen: Gottingen, Germany, 1997.

31.

Spek, A. L. PLATON: A Multipurpose Crystallographic Tool, Utrecht University: Utrecht, The Netherlands, 2010.

32.

Stearns, D. M.; Armstrong, W. H. Inorg. Chem. 1991, 31, 5178.

33.

SAINT+: Bruker Advanced X-ray Solutions, version 7.60A; Bruker AXS Inc.; Madison, Wisconsin, USA, 2008.

34.

(a) Hakimi, M.; Mardani, Z.; Moeini, K.; Mohr, F.; Schuh, E.; Vahedi, H. Z. Naturforsch. 2012, 67b, 452.

35.

(b) Hakimi, M.; Mardani, Z.; Moeini, K. J. Korean Chem. Soc. 2013, 57, 447.

36.

Hakimi, M.; Mardani, Z.; Moeini, K.; Minoura, M.; Raissi, H. Z. Naturforsch. 2011, 66b, 1122.

37.

Nakamoto, K. In Infrared and Raman Spectra of Inorganic and Coordination Compounds, 6th ed.; John Wiley & Sons: Hoboken, 2009; p 208.

38.

(a) Farrugia, L. J. J. Appl. Crystallogr. 1997, 30, 565.

39.

(b) Burnett, M. N.; Johnson, C. K., ORTEP-III, Report ORNL- 6895. Oak Ridge National Laboratory, Oak Ridge, Tennessee, U.S.A., 1996.

40.

Macrae, C. F.; et al. J. Appl. Crystallogr. 2008, 41, 466.

41.

Hakimi, M.; Kukovec, B. M.; Minoura, M. J. Chem. Crystallogr. 2012, 42, 290.

42.

Desiraju, G. R.; Steiner, T. In The Weak Hydrogen Bond: IUCr Monographs on Crystallography 9, Oxford University Press: Oxford, 1999; p 12.