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Thermodynamic Properties and Self Diffusions from Rheological Parameters of Eyring-Halsey Model
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 Title & Authors
Thermodynamic Properties and Self Diffusions from Rheological Parameters of Eyring-Halsey Model
Kim, Nam Jeong;
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 Abstract
The stress relaxation of poly(methyl acrylate)-poly(acrylonitrile) copolymer samples were carried out in air and distilled water at various temperatures using the tensile tester with the solvent chamber. The rheological parameters were obtained by applying the experimental stress relaxation curves to the theoretical equation of the Eyring-Halsey non-Newtonian model. The self diffusion, hole volume, viscosities, and thermodynamic parameters of copolymer samples were calculated from rheological parameters and crystallite size in order to study of flow segments in amorphous region. It was observed that the rheological parameters of these copolymer samples are directly related to the self diffusion, hole volume, viscosities, and thermodynamic parameters of flow segments.
 Keywords
Self diffusion;Hole volume;Thermodynamic parameters;Stress relaxation;Rheological parameters;
 Language
Korean
 Cited by
 References
1.
Krausz, A. S.; Eyring, H. Deformation Kinetics; John Wiley and sons: New York, 1975.

2.
Stachurski, Z. H. Polymer 2002, 43, 7419. crossref(new window)

3.
Abadi, M. T. Composites Science and Technology 2009, 69, 1286. crossref(new window)

4.
Chase, K. W.; Goldsmith, W. Experimental Mechanics 1974, 17, 10.

5.
Gupta, V. B.; Kumar, S. Text. Res. J. 1977, 47, 647.

6.
Kumar, S.; Gupta, V. B. Text. Res. J. 1978, 48, 429. crossref(new window)

7.
Cangialos, D.; Boucher, V. M.; Alegra, A.; Colmenero, J. J. Chem. Phys. 2011, 135, 14901. crossref(new window)

8.
Muralidharan1, V.; Tihminlioglu1, A.; Antelmann1, O.; Duda1, J. L.; Danner, R. P.; Haan, A. D. J. Polym. Sci. 1998, 36, 1713. crossref(new window)

9.
Vrentas, J. S.; Vrentas, C. M. Macromolecules 1995, 28, 4740. crossref(new window)

10.
Vrentas, J. S.; Vrentas, C. M.; Faridi, N. Macromolecules 1996, 29, 3272. crossref(new window)

11.
Demco, D. E.; Rata, G.; Fechete, R.; Blmich, B. Macromolecules 2005, 38, 5647. crossref(new window)

12.
Losch, A.; Salomonovic, R.; Steiner, U.; Fetters, L. J.; Klein, J. J. Polym. Sci. 1995, 33, 1821. crossref(new window)

13.
Clarke, N.; Colley, F. R.; Collins, S. A.; Hutchings, L. R.; Thompson, R. L. Macromolecules 2006, 39, 1290. crossref(new window)

14.
Neuhusler, S.; Richtering, W. Colloids Surf. 1995, 51, 39.

15.
Gell, C. B.; Graessley, W. W.; Fetters, L. J. J. Polym. Sci. 1997, 35, 1933.

16.
Berend, K.; Richtering, W. Colloids Surf. 1995, 119, 101.

17.
Zhu, Q. Z.; Shao, J. F.; Mainguy, M. International Journal of Plasticity 2010, 26, 586. crossref(new window)

18.
Berbenni, S.; Collard, C.; Favier, V.; Berveiller, M. International Journal of Plasticity 2010, 26, 310. crossref(new window)

19.
Darabi, M. K.; Abu Al-Rub, R. K.; Masad, E. A.; Huang, C.-W.; Little, D. N. International Journal of Solids and Structures 2011, 48, 191. crossref(new window)

20.
Abu Al-Rub, R. K.; Darabi, M. K. International Journal of Plasticity 2012, 34, 61. crossref(new window)

21.
Kim, N. J. Polymer(Korea) 2013, 37, 135.