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Electrochemical Study of the Copolymer Formation Between o-Chlorophenol and o-Hydroxyphenol
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 Title & Authors
Electrochemical Study of the Copolymer Formation Between o-Chlorophenol and o-Hydroxyphenol
Sayyah, Said M.; Abd-Elrehim, Said S.; Azooz, Rehab E.; Mohamed, Fatma;
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 Abstract
Electrochemical copolymerization of o-chlorophenol (oCP) with o-hydroxyphenol (oHP) was carried out in aqueous by using cyclic voltammetry (CV) technique. In addition, CV was used to evaluate the differences in electrochemical characteristics of the copolymer in comparison with the corresponding homopolymers, poly(o-chlorophenol) (PoCP) and poly(o-hydroxyphenol) (PoHP). The variation of peak currents with respect to sweep rates was compared between copolymer and homopolymers, PoCP and PoHP, films. Further support for copolymer characterization was obtained by recording UV-visible, IR spectra and elemental analysis. The mechanism of the electrochemical polymerization has been discussed. The monomer reactivity ratios ( and ) were calculated using Fineman-Rss method and was found to be 0.4 and 1.3 repetitivelly and the copolymer structure is a block structure and more rich in oHP units.
 Keywords
Block copolymers;Electropolymerization;Reactivity ratios;Phenols;
 Language
English
 Cited by
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