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Surfactant-enhanced Soil Washing using Tween and Tergitol Series Surfactants for Kuwait Soil Heavily Contaminated with Crude Oil
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 Title & Authors
Surfactant-enhanced Soil Washing using Tween and Tergitol Series Surfactants for Kuwait Soil Heavily Contaminated with Crude Oil
Heo, Hyojin; Lee, Minhee;
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Batch experiments were performed to investigate the feasibility of a surfactant-enhanced soil washing process for soils heavily contaminated with crude oil in Kuwait. TPH concentration of the contaminated soil was 223,754 mg/kg, sampled from the bottom of a vaporized oil extraction pond in the Burgan reservoir field. Commercialized eight nonionic surfactants (Tween and Tergitol series) were used to measure the aqueous solubility for the crude oil. Among them, two Tergitol surfactants were used to evaluate the TPH removal efficiency of the surfactant-enhanced soil washing for heavily contaminated Kuwait soil. The solubility of the crude oil in surfactant solution was in the order Tergitol 15-S-7 > Tergitol 15-S-9 > Tergitol 15-S-12 > Tween-80 > Tween-20 > Tween-60, which showed that the crude oil solubilities of the Tergitol series were higher than those of the Tween series. The TPH removal efficiencies of 2% and 5% Tergitol 15-S-9 solution were 59% and 65%, respectively. Because the residual TPH concentration in the washed soil was still higher than the clean-up level (10,000 mg/kg), the soil washing process was repeated five times. After the fifth washing, the residual TPH concentration in the soil went down to 7,680 mg/kg and its removal efficiency was 97%.
Crude oil;Soil washing;Surfactant;Tergitol;Tween;
 Cited by
Abdul, A.S. and Gibson, T.L., 1991, Laboratory studies of surfactant-enhanced washing of polychlorinated biphenyls from sandy material, Environ. Sci. Technol., 25(4), 665-671. crossref(new window)

Deshpande, S., Shiau, B.J., Wade, D., Sabatini, D.A., and Harwell, J.H., 1999, Surfactant selection for enhancing ex situ soil washing, Water Res., 33(2), 351-360. crossref(new window)

Griffiths, R.A., 1995, Soil-washing technology and practice, J. Hazard. Mater., 40(2), 175-189. crossref(new window)

Heo, H., 2015, Application of the surfactant-enhanced soil washing to crude oil contaminated soils in Kuwait, Thesis of Ph. D, Pukyong National University.

Huguenot, D., Moisset, E., van Hullebusch, E.D., and Oturan, M.A., 2015, Combination of surfactant enhanced soil washing and electro-Fenton process for the treatment of soils contaminated by petroleum hydrocarbons, J. Environ. Manage., 153, 40-47. crossref(new window)

Khalladi, R., Benhabiles, O., Bentahar, F., and Moulai-Mostefa, N., 2009, Surfactant remediation of diesel fuel polluted soil, J. Hazard. Mater., 164, 1179-1184. crossref(new window)

KME (Korean ministry of environment), 2011, Development of bioremediation technology to clean up of oil contaminated soil in Kuwait, Final Report/2010-13004-0004-0.

Kuyukina, M.S., Ivshina, I.B., Makarov, S.O., Litvinenko, L.V., Cunningham, C.J., and Philp, J.C., 2005, Effect of biosurfactants on crude oil desorption and mobilization in a soil system, Environ. Int., 31, 155-161. crossref(new window)

Lee, M., 2001, Column and box experiments for surfactant enhanced remediation of organic pollutants (NAPL), J. Geol. Soc. Kor., 37, 45-56.

Lee, M., Kang, H.M., and Do, W.H., 2005, Application of nonionic surfactant-enhanced in situ flushing to a diesel contaminated site, Water Res., 39, 139-146. crossref(new window)

Lima, A.T., Kleingeld, P.J., Heister, K., and Loch, J.P.G., 2011, Removal of PAHs from contaminated clayey soil by means of electro-osmosis, Sep. Pur. Technol., 79, 221-229. crossref(new window)

Mittal, K.L., 1979, Solution Chemistry of Surfactants, Plenum Publishing Corporation, New York, USA, 961 p.

Mulligan, C.N., Yong, R.N., and Gibbs, B.F., 2001, Surfactant-enhanced remediation of contaminated soil: a review, Eng. Geol., 60, 371-380. crossref(new window)

Paria, S., 2008, Surfactant-enhanced remediation of organic contaminated soil and water, Adv. Coll. Int. Sci., 138, 24-58. crossref(new window)

Park, S.W., Lee, J.Y., Yang, J.S., Kim, K.J., and Baek, K., 2009, Electrokinetic remediation of contaminated soil with waste-lubricant oils and zinc, J. Hazard. Mater., 169, 1168-1172. crossref(new window)

Rosen, M.J. and Kunjappu, J.T., 2012, Surfactants and Interfacial Phenomena, John Wiley & Sons, USA.

Saenger, P., 1994, Cleaning up the Arabian Gulf: Aftermath of an Oil Spill, School of Environment, Science and Engineering Papers, Southern Cross University, USA.

Simmons, M.R., 2002, The World’s Giant Oilfields, M. King Hubbert Center for Petroleum Supply Studies, Simmons and Company International, Final Report, 62 p.

Tsomides, H.J., Hughes, J.B., Thomas, J.M., and Ward, C.H., 1995, Effect of surfactant addition on phenanthrene biodegradation in sediments, Environ. Toxic. Chem., 14(6), 953-959. crossref(new window)

Um, J., Lee, G., Song, S., Hong, S., and Lee, M., 2013, Pilot scale feasibility test of In-situ soil flushing by using ‘Tween 80’ solution at low concentration for the xylene contaminated site, J. Soil. Groundw. Environ., 18(6), 38-47. crossref(new window)

Urum, K., Grigson, S., Pekdemir, T., and McMenamy, S., 2006, A comparison of the efficiency of different surfactants for removal of crude oil from contaminated soils. Chemosphere, 62, 1403-1410. crossref(new window)

Urum, K., Pekdemir, T., and Çopur, M., 2004, Surfactants treatment of crude oil contaminated soils. J. Coll. Int. Sci., 276, 456-464. crossref(new window)

Volkering, F., Breure, A. M., and Rulkens, W. H., 1998, Microbiological aspects of surfactant use for biological soil remediation. Biodegradat., 8, 401-417.

West, C.C. and Harwell, J.H., 1992, Surfactants and subsurface remediation, Environ. Sci. Technol., 26, 2324-2340. crossref(new window)

Yang, J.W., Yang, J.S., Lee, Y.J., Kim, S.H., and Shin, H.J., 2008, Effect of surfactant types on washing of diesel-contaminated soil, J. Soil Groundw. Environ., 13(3), 8-14.

Yeom, I.T., Ghosh, M.M., Cox, C.D., and Robinson, K.G., 1995, Micellar solubilization of polycyclic aromatic hydrocarbons in coal tar-contaminated soils, Environ. Sci. Technol., 29, 3015-3021. crossref(new window)