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Effects of Lithium Bis(Oxalate) Borate as an Electrolyte Additive on High-Temperature Performance of Li(Ni1/3Co1/3Mn1/3)O2/Graphite Cells
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 Title & Authors
Effects of Lithium Bis(Oxalate) Borate as an Electrolyte Additive on High-Temperature Performance of Li(Ni1/3Co1/3Mn1/3)O2/Graphite Cells
Jeong, Jiseon; Lee, Hyewon; Lee, Hoogil; Ryou, Myung-Hyun; Lee, Yong Min;
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The effects of electrolyte additives, lithium bis(oxalate)borate (LiBOB), fluoroethylene carbonate (FEC), vinylene carbonate (VC), 2-(triphenylphosphoranylidene) succinic anhydride (TPSA), on high-temperature storage properties of /graphite are investigated with coin-type full cells. The 1 wt.% LiBOB-containing electrolyte showed the highest capacity retention after high temperature () storage for 20 days, 86.7%, which is about 5% higher than the reference electrolyte, 1.15M lithium hexafluorophosphate () in ethylene carbonate/ethyl methyl carbonate (EC/EMC, 3/7 by volume). This enhancement is closely related to the formation of semi-carbonate compounds originated from anions, thereby resulting in lower SEI thickness and interfacial resistance after storage. In addition, the 1 wt.% LiBOB-containing electrolyte also exhibited better cycle performance at 25 and than the reference electrolyte, which indicates that LiBOB is an effective additive for high-temperature performance of /graphite chemistry.
electrolyte additive;high temperature storage;lithium bis(oxalate) borate;solid electrolyte;interphase;
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