JOURNAL BROWSE
Search
Advanced SearchSearch Tips
Isomeric Effects on Volatilization of 1,3-Dichloropropene Fumigant in Soil
facebook(new window)  Pirnt(new window) E-mail(new window) Excel Download
 Title & Authors
Isomeric Effects on Volatilization of 1,3-Dichloropropene Fumigant in Soil
Kim, Jung-Ho; Mallavarapu, Megharaj;
  PDF(new window)
 Abstract
The fumigant 1,3-dichloropropene (1,3-D) was recently proposed as a direct replacement for methyl bromide () in soil fumigation. This study was conducted to better understand behavior phase partitioning, diffusion and volatilization of 1,3-D as affected by isomer. The Henry's law constant(KH) of cis-1,3-D and trans-1,3-D was 0.058 and 0.037 at , respectively. of cis form of 1,3-D was higher than that of trans form of 1,3-D. To compare with volatilization of 1,3-D isomer, soil column [70 cm (length)12 cm (i.d.)] included a shank injection at 30 cm with 300 kg . Maximum cis-1,3-D and trans-1,3-D concentration reached 57 mg and 39 mg at 30 cm depth at 1h after application. Cumulatively, after 10 days, 51.8% and 43.57% of applied cis-1,3-D and trans-1,3-D was emitted via volatilization, respectively. The total losses of cis-1,3-D were significantly greater than that of trans-1,3-D. Finally, cis-1,3-D and trans-1,3-D, such as isomer are dominant of 1,3-D fates in soil.
 Keywords
Fumigant;Ozone-depleting chemicals;Isomer;1,3-dichloropropene;Phase partitioning;Diffusion;Volatilization;
 Language
English
 Cited by
 References
1.
Baker L. W., D. L. Fitzell, J. N. Seiber, T. R. Parker, T. Shibamoto, M. W. Poore, K. E. Longley, R. P. Tomlin, R. Propper and D. W. Duncan, 1996, Ambient air concentration of pesticides in California, Environ. Sci. Technol., 30, 1365-1368 crossref(new window)

2.
Kim J. H., 2006, Multi analysis of fumigants in soil and water, J. Environ. Toxicol., 21(4), 365-373

3.
Anonymous, 2000, Protection of stratospheric ozone: Incorporation of Clean Air Act amendments for restrictions in Class I, Group VI controlled substances. Federal Register, 65, 70795-70804

4.
Park M. K., J. H. Kim and R. S. Dungan, 2004, Sorption of the fumigant 1,3-dichloropropene on soil, J. Environ. Sci. Health, B39(4), 603-612 crossref(new window)

5.
Aspelin A. L. and A. H. Grub, 1999, Pesticide Industry Sales and Usage: 1996 and 1997 Market Estimates, The U.S. Environmental Protection Agency, Washington, D.C., Publication No. 733-R-99-001

6.
http://www.atsdr.cdc.gov/tfact40.html

7.
Gan J., S. R. Yates, D. Wang and F. F. Ernst, 1998, Effect of application methods 1,3-dichloropropene volatilization from soil under controlled conditions, J. Environ. Qual., 27, 432-438 crossref(new window)

8.
Papiernik S. K., S. R. Yates and J. Gan, 2001, An approach for estimating the permeability of agricultural films, Environ. Sci. Technol., 35, 1240-1246 crossref(new window)

9.
Arvieu J. C., 1983, Some physico-chemical aspects of methyl bromide behaviour in soil, Acta Hortic., 152, 267-274

10.
Gan J. and S. R. Yates, 1996, Degradation and phase partition of methyl iodide in soil, J. Agric. Food Chem., 44, 4001-4008 crossref(new window)

11.
Yates S. R and J. Gan, 1998, Adsorption and degradation of propargyl bromide as a soil fumigant, J. Agric. Food Chem., 46, 755-761 crossref(new window)

12.
Leistra M., 1970, Distribution of 1,3-dichloropropene over the phases in soil, J. Agric. Food Chem., 18, 1124-1126 crossref(new window)

13.
Gan, J., S. R. Yates, D. Crowley and J. O. Becker, 1998, Acceleration of 1,3-dichloropropene degradation by organic amendments and potential application for emissions reduction, J. Environ. Qual., 27, 408-414 crossref(new window)

14.
Kim J. H., 2007, Transformation for 1,3-dichloropropene of soil fumigant in water and soil, J. Environ. Sci., 16(2), 1463-1468 crossref(new window)

15.
Gan J., W. J. Farmer, S. K. Papiernik, R. S. Dungan and S. R. Yates, 2003, Organic matter effects on phase partition of 1,3-dichloropropene in soil, J. Agric. Food Chem., 51, 165-169 crossref(new window)

16.
Kim J. H., S. K. Papiernik, W. J. Farmer, J. Gan and S. R. Yates, 2003, Effect of formulation on the behavior of 1,3-dichloropropene in soil, J. Environ. Qual., 32, 2223-2229 crossref(new window)

17.
Peng J. and A. Wan, 1997, Measurement of Henry's constants of high volatility organic compounds using a headspace autosampler, Environ. Sci. Technol., 31, 2998-3003 crossref(new window)

18.
Gan J., C. Hutchinson, F. F. Ernst, J. O. Becker and S. R. Yates, 2000, Column system for concurrent assessment of emission potential and pest control of soil fumigants, J. Environ. Qual., 29, 657-661 crossref(new window)

19.
Gan J., J. O. Becker, F. F. Ernst, C. Hutchinson, J. A. Knuteson and S. R. Yates, 2000, Surface application of ammonium thiosulfate fertilizer to reduce volatilization of 1,3-dichloropropene from soil, Pest Manag. Sci., 56, 264-270 crossref(new window)

20.
Tomlin C., 1994, The Pesticide Manual. 10th Ed. British Crop Protection Council, U.K., 307-309

21.
Wang Q., J. Gan, S. K. Papiernik and S. R. Yates, 2001, Isomeric effects on thiosulfate transformation and detoxification of 1,3-dichloropropene, Environ. Sci. Technol., 31, 3686-3691 crossref(new window)