Advanced SearchSearch Tips
Removal of Rhodamine B in Water by Ultraviolet Radiation Combined with Electrolysis(II)
facebook(new window)  Pirnt(new window) E-mail(new window) Excel Download
 Title & Authors
Removal of Rhodamine B in Water by Ultraviolet Radiation Combined with Electrolysis(II)
Kim, Dong-Seog; Park, Young-Seek;
  PDF(new window)
This study has carried out to evaluate the effect of NaCI as electrolyte of single (electrolysis and UV process) and complex (electrolysis/UV) processes for the purpose of removal and mineralization of Rhodamine B (RhB) dye in water. It also evaluated the synergetic effect on the combination of electrolysis and UV process. The experimental results showed that RhB removal of UV process was decreased with increase of NaCl, while RhB removal of electrolysis and electrolysis/UV process was increased with increase of NaCI. The decolorization rate of the RhB solution in every process was more rapid than the mineralization rate identified by COD removal. The latter took longer time for further oxidation. Absorption spectra of an aqueous solution containing RhB showed a continued diminution of the RhB concentration in the bulk solution: concomitantly, no new absorption peaks appeared. This confirmed the decolorization of RhB, i.e., the breakup of the chromophores. It was observed that RhB removal in electrolysis/UV process is similar to the sum of the UV and electrolysis. However, it was found that the COD of RhB could be degraded more efficiently by the electrolysis/UV process than the sum of the two individual process. A synergetic effect was demonstrated in electrolysis/UV process.
Electrolysis/UV process;Absorption spectra;Dye;COD;NaCI;
 Cited by
Boron-doped Diamond 전극을 이용한 Rhodamine B와 N, N-Dimethyl-4-nitrosoanilin의 전기화학적 분해에 반응표면분석법의 적용과 공정 최적화,김동석;박영식;

한국환경보건학회지, 2010. vol.36. 4, pp.313-322 crossref(new window)
수처리용 유전체장벽 플라즈마 반응기에 대한 기초 연구,김동석;박영식;

Journal of Environmental Science International, 2011. vol.20. 5, pp.623-630 crossref(new window)
E. coli 불활성화를 위한 단일 소독 공정의 비교,김동석;송승구;박영식;

KSBB Journal, 2010. vol.25. 1, pp.25-32
불용성 전극의 Dye 제거 성능과 산화제 생성 비교,유영억;김동석;

Journal of Environmental Science International, 2011. vol.20. 10, pp.1273-1284 crossref(new window)
수중 플라즈마 공정을 이용한 Rhodamine B 염료의 제거,김동석;박영식;

한국환경보건학회지, 2011. vol.37. 3, pp.218-225 crossref(new window)
개선된 플라즈마 공정을 이용한 Ralstonia Solanacearum 불활성화에 관한 연구,김동석;박영식;

Journal of Environmental Science International, 2014. vol.23. 3, pp.369-378 crossref(new window)
고체 고분자 전해질(SPE)을 이용한 전기분해 공정에서 Rhodamine B 분해,박영식;

한국환경보건학회지, 2014. vol.40. 2, pp.137-146 crossref(new window)
기-액 혼합 플라즈마 방전 시스템에서 화학적 활성종의 생성,김동석;박영식;

한국물환경학회지, 2014. vol.30. 4, pp.394-402 crossref(new window)
Kim T. H., Park C. H., Lee J., Shin E. B., Kim S. Y., 2002, Pilot scale treatment of textile wastewater by combined processes (fluidized biofilm process-hemical coagulation -electrochemical oxidation), Wat. Res., 36, 3979-3988 crossref(new window)

Kim T. H., Park C. H., Kim S. Y., 2008, Adsorption of textile wastewater on sawdust, J. of KSEE., 30(4), 439-445

Ha D. Y., Cho S. H., 2003, Comparison of UVIH$_{2} O$_{2}$ and TiO$_{2}$ photocatalytic oxidation in the dyeing wastewater treatment efficiency, J. of KSEE., 25 9),1123-1131

양용운, 1996, 염색폐수의 색도제거기술현황 및 대책 방안, 11, 2-11

Andeozzi R., Caprio V., Amedo I., Marotta R., 1999, Advanced oxidation process(AOP) for water purification and recovery, Cat. Today, 53(1), 55-59 crossref(new window)

Herrmann J. M., 1999, Heterogeneous photocatalysis:fundamentals and applications to the removal of various types of aqueous pollutants, Cat. Today, 53(1), 115-129 crossref(new window)

김동석, 박영식, 2009, 산화제 생성율이 높은 촉매성 산화물 전극(DSA)의 개발에 관한 연구,(2), 한국환경과학회지, 18(1), 61-72

Chen G., 2004, Electrochemical technologies in wastewater treatment, Sep. Purif. Technol., 38, 11-41 crossref(new window)

Coast C. R, Botta C. M. R, Espindola E. L. G., Oliva P., 2008, Electrochemical treatment of tannery wastewater using DSA${\circledR}$ electrodes, J. of Hazard. Mater., 153, 616-627 crossref(new window)

Jiittner K, Galla U., Schmieder H, 2000, Electrochemical approaches to environmental problems in the process industry, Electrocmica Acta, 45, 2575-2594 crossref(new window)

김홍석, 서인석, 최일환, 김연권, 김지연, 이진영, 2004, 용존공기를 이용한 소독능 향상 전기분해 소독공정개발, 한국물환경학회.대한상하수도학회 공동추계학술발표회 논문집, 625-628

Panizza M., Barbucci A., Ricotti R., Cerisola G., 2007, Electrochemical degradation of methylene blue, Sep. Purif. Technol., 54, 382-387 crossref(new window)

Daneshvar N., Aber S., Vatanpour V., Rsoulifard, H., 2008, Electro-Fenton treatment of dye solution containing Orange II: influence of operational parameters, J. of Electroanal. Chem., 615(2), 165-174 crossref(new window)

박영식, 김동석, 2008, 전해질 첨가 전기/UV 공정을 이용한 염료의 색 제거, 한국환경과학회 추계학술발표대회, 17(1), 368-372

박영식, 2008, 전기분해와 UV 조사에 의한 Rhodamine B의 제거(1), 한국환경보건학회지, 34(6), 439-445

Piscopo A., Robert D., Weber J. V., 2001, Influence of pH and chloride anion on the photocatalytic degradation of organic compounds part I. effect on the benzamide and para-hydroxy benzoic acid in TiO$_{2}$aqueous solution, Appl. Cat. B: Environ., 35, 117-124 crossref(new window)

17. l? Categoryld=9&iCategoryId Main=O&iGoodsId=G 12T5VH&iCurrentPage= 1

APH-AWWA-WPCE, 1992, Standard Methods for the Examination of Water and Wastewater, 18th Ed., APHA, Washington D.C..

Raghu S., Basha C. A., 2007, Electrochemical treatment of Procion Black 5B using cylindrical flow reactor-a pilot plant study. J. of Hazard. Mat. B, 139, 381-390 crossref(new window)

Abdullah M., Low, G. K., Matthews R. W., 1990, Effects of common inorganic anions on rates of photocatalytic oxidation of organic carbon over illuminated titanium dioxide, J. Phys. Chem., 94, 6820-6825 crossref(new window)

박영식, 김동석, 2007, 전기화학적 소독에 의한 Legionella pneumophila 불활성화, 한국물환경학회지, 23(5), 613-619

Bejankiwar R., Lalman J. A., Seth R., Biswas N., 2005, Electrochemical degradation of 1,2-Dichloroethane(DCA) in a synthetic ground water medium using stainless-steel electrodes, Wat. Res., 39, 4715-4724 crossref(new window)

김동석, 박영식, 2007, 불용성 전극을 이용한 Rhodamine B의 전기화학적 탈색, 한국물환경학회지, 23(3), 377-384

박영식, 안갑환, 2001, 오존 및 UV 후처리가 염색폐수의 COD와 색도 제거에 미치는 영향, 환경위생학회지, 27(4), 93-98

안갑환, 권수광, 박영식, 2004, Rhodamine B의 오존등/광촉매 탈색, 대한환경공학회지, 26(10), 1063-1069

Zhao J., Wu T., Wu K., Oikawa K., Hidaka H., Serpone N., 1998, Photoassisted degradation of dye pollutants. 3. Degradation of the cationic dye Rhodamine B in aqueous anionic surfactant TiO$_{2}$ dispersions under visible light irradiation: evidence for the need of substrate adsorption on TiO$_{2}$ particles, Environ. Sci. Technol., 32, 2394-2400 crossref(new window)

Park Y. S., 2008, Indirect oxidation of dye using quaternary dimensionally stable anode (DSA) with High generation rate of oxidants, Korea Research Foundation, 2007 Regional University Researchers Program, Final Report(EOOI15), 8-22