Advanced SearchSearch Tips
Synthesis of Pentadentate Nitrogen-Oxygen(N2O3) Ligands with Substituting Groups and Determination of Stability Constants of Their Transition Metal(II) Complexes
facebook(new window)  Pirnt(new window) E-mail(new window) Excel Download
 Title & Authors
Synthesis of Pentadentate Nitrogen-Oxygen(N2O3) Ligands with Substituting Groups and Determination of Stability Constants of Their Transition Metal(II) Complexes
Kim, Seon-Deuk; Lee, Hye-Won; Jin, Gyoung-Rok;
  PDF(new window)
Hydrochloric acid salt of a new pentadentate ligand, N,N'-Bis(2-Hydroxybenzyl)-1,3-diamino-2-propanol(H-BHDP 2HCl) was synthesized. Br-BHDP 2HCl, CI-BHDP 2HCl, 2HCl and -BHDP 2HCl having Br, Cl, and substituents at 5-position of the phenol group of H-BHDP 2HCl were also synthesized. The potentiometry study in aqueous solution revealed that the proton dissociations of the synthesized ligands occurred in four steps and their order of the calculated overall proton dissociation constants() was Br-BHDP < Cl-BHDP < H-BHDP < < . The order showed a similar trend to that of Hammett substituent constants(). The order of the stability constants() was Co(II) < Ni(II) < Cu(II) < Zn(II) < Cd(II) < Pb(II). The order in their stability constants () of each transition metal complex agreed with that of the overall proton dissociation constants ().
Pentadentate ligand;Dissociation constants;Stability constants;
 Cited by
새로운 질소-산소(N3O2)계 다섯 자리 리간드의 합성과 중금속(II) 이온들의 착물 안정도상수에 대한 치환기효과,김선덕;이혜원;설종민;

Journal of Environmental Science International, 2010. vol.19. 7, pp.849-860 crossref(new window)
Kim E. J., Kim Y. S., Choi J. M., 2008, Studies on Solvent Extraction Using Salphen for Separative Determination of Trace Fe(II) and Fe(III) in Water Sample, Bull. Korean Chern. Soc., 29(1), 99-103 crossref(new window)

Agett J., Khoo A. W., 1981, Richardson R. A., Solvent Extraction of Cu(II) by Schiff Base-Il , J. Inorg. Chem., 43, 1867-1882

Agett J., Richardson R. A., 1970, Solvent Extraction of Cu(II) by Schiff Bases, Analytical Chimica Acta, 50, 269-273 crossref(new window)

이대운, 이항, 유의경, 1979, 킬레이트 시약으로 처리한 음이온 교환수지에 의한 금속이온의 선택적 흡착에 관한 연구, 대한화학회지, 23(3), 141-151

지상현, 고석오, 2008, 킬레이트제를 이용한 토양에서의 중금속 용출제거 평가, 한국폐기물학회지, 25(4), 287-294

김영근, 김정래, 이우근, 2006, 산화-용매추출을 이용한 소각비산재로부터 Cu와 Zn의 회수, 23(7), 623-628

Kim Y. S., In G., Kim M. H., Choi J. M., 2006, Fundamental Study on Solvent Sublation Using Salphen and Its Application for Separative Detemination of Trace Ni(II), Co(II) and Cu(II) in Water Samples, Bull. Korean Chem. Soc., 27(11), 1757-1762 crossref(new window)

Joshaghani M., Gholivand M. B., Ahmadi F., 2008, Spectrophotometric and conductometric study of complexation of salophen and some transition metal ions in nonaqueous polar solvents, Spec. Acta. Part A., 70, 1073-1078 crossref(new window)

Rabie U. M., Assran A. S. A., Abou-El-Wafa M. H. M., 2008, Unsymmetrical Schiff base functionalize as bibasic tetradentate(ONNO) and monobasic tridentate(NNO) ligands complexation with some transition metal ions, J. Mole. stru., 872, 113-122 crossref(new window)

Tao R. J., Li F. A., Cheng Y. X., Zang S. Q., Wang Q. L., Niu J. Y., Liao D. Z., 2006, Synthesis, crystal structure and magnetic properties of a chain coordination polymer [[Cu_4L_2(H_2O)]{\cdot}H_2O]_n , Inorg. Chim. Acta., 359, 2053-2058 crossref(new window)

Pradeep C. P., Zacharias P. S., Das S. K., 2006, Synthesis and structural characterization of a carboxylate bridged tetranuclear copper complex derived from reduced Sciff base asymmetric compartmental ligand containing an amino acid side arm, Inorg. Chem. Com., 9, 1071-1074 crossref(new window)

Jancso A., Paksi Z., Mikkola S. A., Rockenbauer A., Gajda T., 2005, Iron(III) and copper(II) complexes of an asymmetric, pentadentate salen-like ligand bearing a pendant carboxylate group, J. lnorg. Biochem., 99, 1480-1489 crossref(new window)

Biava H., Palopoli C, Shova S., Gaudio M. D., Daier V. M., Gonazlez-Sierra M., Tuchagues J. P., Signorella S., 2006, New dimanganese(III) complexes of pentadentate ($N_2O_3$) Schiff base ligands with the $[Mn_2(\mu-OAc)(\mu-OR)_2]^{3+}$ core: Synthesis, characterization and mechanistic studies of $H_2O_2$ disproportionation, J. Inorg. Biochem., 100, 1660-1671 crossref(new window)

Plass W., 1996, Synthesis and characterization of a $VO^{3+}$ complex of a pentadentate amine alcohol ligand: towards hydrolytically stable ligands forming medel complexes for vanadium-dependent haloperoxidases, Inorg. Chim. Acta., 244, 221-229 crossref(new window)

Gupta K. C., Sutar A. K., 2008, Catalytic activity of polymer anchored N,$N^{\prime}$-bis(o-hydroxyacetophenone) ethylene diamine Schiff base complexes of Fe(III), Cu(III) and Zn(III) ions in oxidation of phenol, Rea & Fun. Poly., 68, 12-26 crossref(new window)

Gupta K. C., Sutar A. K., 2008, Catalytic activities of Schiff base transition metal complexes, Coor. Chem. Rev., 252, 1420-1450 crossref(new window)

Kureshy R. I., Khan N. H., Abdi S. H. R., Iyer P., 1997, Synthesis of catalytically active polymer-bound Mn(III) salen complexes for enantioseiective epoxidation of styrene derivatives, Rea. & Fun. Poly., 34, 153-160 crossref(new window)

Naeimi H., Salimi F. K., Rabiei K., 2006, Mild and convenient one pot synthesis of Schiff bases in the presence of $P_2O_5/AlO_3$ as new catalyst under solvent- free conditions, J. Mole. Cata. A: Chem., 260, 100-104 crossref(new window)

김선덕, 이도협, 2006, 새로운 N,N,O계 세 자리 리간드의 합성과 전위차적정 법에 의한 전이금속 착물의 안정도상수의 결정, 한국환경과학회지, 15(8), 799-809 crossref(new window)

Kim S. D., Jin G. R., 2006, Synthesis of new $N_2O_2$ tetradentate ligands and the substituent effect on the stability constants of the transition metal complexes, Analytical Science & Technology, 19(2), 131-141

김선덕, 김준광, 이경호, 2007, 중금속이온 분리를 위한 새로운 네 자리 $N_2O_2$계 리간드의 합성 및 착화합물의 안정도상수 결정, 한국환경과학회지, 16(8), 913-920

Martell A. E., Motekaitis R. J., 1992, Detemination and Use of Stability Constants. 2nd ed. VCH, N. Y

Motekaitis R. J., Martell A. E., 1992, Stabilities of Metal Complexes of the Meso and SS Isomers of Oxydisuccinic Acid. Inorg. Chem., 31, 11-15 crossref(new window)

Parsons G. H., Rochester C H., 1975, Acid Ionization Constants of 4-Substitutes Phenols in Methanol+Water Mixtures. J. Chem. Soc. Faraday, 71, 1058-1068 crossref(new window)

Koseoglu F., Kilic E., Uysal D., 1995, Protonation constants of some substituted 2-hydroxy-I-naphthalideneanilines in dioxan-water mixtures, Talanta., 42, 1875-1882 crossref(new window)

Kilic F., Canel E., Yilmaz E., 1994, Protonation constants of some substituted salicylidineanilines in ethanol-water mixtures, Analytica Chimica Acta., 293, 87-94 crossref(new window)

Jaffe H. H., 1953, A Reexamination of the Hammett Equation, Chem. Rev., 53, 191-261 crossref(new window)

Hoefnagel A. J., Hoefnagel M. A., Wepster B. M., 1978, J. Org. Chem., 43(25), 4720-4745 crossref(new window)

Walkwiak W., Stewart L. E., Lee H. K., Szech B. P., Bartsch R. A., Anal. Cheme., 1986, Compectitive Solvent Extrction of Alkaline-Earth Cations into Chloroform by Lipophilic Acyclic Diionzable Polyethcrs, Anal. Chem., 58, 188-191 crossref(new window)

Kang S. I., Czech A., Czech B. P., Stewart L. E., Bartsch R. A., 1985, Compectitive Solvent Extrction of Alkaline-Earth Cations into Chloroform by Lipophilic Acyclic Polyether Dicarboxylic Acids, Anal. Chem., 57, 1713-1717 crossref(new window)

Ercorani, G., Mandolini. L., Masci, B., 1981, Template Effects. 3. The Quantitative Determination of the Catalytic of Alkali and Alkaline Earth Cations in the Formation of Benzo-18-crown-6 in Methanol Solution, J. Am. Chem. Soc., 103, 2780 crossref(new window)

Hall E. A., Amma E. L., 1969, Macrocyc1ic Effect on the Stability of Copper(II) Tetraamine Complexes, J. Am. Chem. Soc., 5, 6540-6541

Coleman W. M., 1981, Relationships between Ligand Carbon-13 Chemical Shifts and Reduction Potentials of Mn(Ill) Complex, Inorg. Chim. Acta., 53, 191-193 crossref(new window)

Juan A. A., Antonio B., Enrique G. E., Santoago V. L., Jose M. L., Jose A. R., Conxa S., 1994, Synthesis, Protonation and Co-ordina tion Abilities of the Open-chain Polyamine 4,8,11,15-Tetraazaocta decane- 1,18-diamine, J. Chem. Soc., Dalton Trans, 637-634