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Adsorption of CO2 on Amine-impregnated Mesorporous Silica
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 Title & Authors
Adsorption of CO2 on Amine-impregnated Mesorporous Silica
Choi, Sung-Woo;
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Adsorption experiment of carbon dioxide was performed on MCM41 silica impregnated with two kinds of EDA(ethylenediamine) and MEA(monoethanolamine). The prepared adsorbents were characterized by BET surface area, X-ray diffraction and FT-IR. The capture study was investigated in a U type packed column with GC/TCD. The results of XRD for MCM-41 and amine-impregnated MCM41 showed typical the hexagonal pore system. BET results showed the MCM 41 impregnated amine to have a surface area of 141 to 595 and FT-IR revealed a N-H functional group at about 1400 to 1600. The adsorption capacity on EDA and MEA was as follow: MCM41-EDA30 > MCM41 -EDA40 >MCM41-EDA20 >MCM-EDA10 and MCM41-MEA40 >MCM41-MEA30 > MCM41-MEA20> MCM41-MEA10. The MCM41-EDA30 showed the highest adsorption capacity due to physical adsorption and chemical adsorption by amino-group content. The results suggest that mesoporous media with EDA is effective adsorbent for capture from flue gases.
Adsorption; capture;Porous media;Impregnation;MCM41;
 Cited by
CO2 흡착을 위한 Ethylenediamine 함침 MCM41의 특성 분석,이철규;최성우;

Journal of Environmental Science International, 2012. vol.21. 6, pp.705-711 crossref(new window)
Adsorption Characteristic of Carbon Dioxide on Activated Carbon Impregnated with Piperazine, Journal of the Environmental Sciences international, 2013, 22, 7, 847  crossref(new windwow)
박예원, 백일현, 박상도, 이재욱, 박소진, 2007, MEA (monoethanolamine)함침 메조포러스 물질을 이용한 $CO_2$ 회수, 화학공학, 45(6), 573-581.

이동환, 감상규, 이송우, 이민규, 2010, 함침농도와 $CO_2$ 가스 유입농도에 따른 활성탄의 흡착특성, 한국환경과학회지, 26(12), 1403-1407. crossref(new window)

에너지경제연구원, 2010,

Aaron, D., Tsouris, C., 2005, Separation of $CO_2$ from flue gas: a review, Sep. Sci. Technol., 40, 321-348. crossref(new window)

Aroua, M. K., Daud, W. M. A. W., Yin, C. Y., Adinata, D., 2008, Adsorption capacities of carbon dioxide, oxygen, nitrogen and methane on carbon molecular basket derived from polyethyleneimine impregnation on microporous palm shell activated carbon, Sep. Purif. Technol., 62, 609-613 crossref(new window)

Belmabkhout, Y., Serna-Guerrero, R., Abdelhamid Sayari, A., 2009, Adsorption of $CO_2$ from dry gases on MCM41 silica at ambient temperature and high pressure. 1: pure $CO_2$ adsorption, Chem. Eng. Sci., 64(17), 3721-3728. crossref(new window)

Biz, S., Occelli, M. L., 1998, Synthesis and characterization of mesostructured materials, Catal. Rev. Sci. Eng., 40, 329-407. crossref(new window)

Chena, C., Sona, W. J., Youb, K. S., Ahnb, J. W., Ahna, W. S., 2010, Carbon dioxide capture using amine-impregnated HMS having textural mesoporosity, Chem. Eng. J., 161, 46-52. crossref(new window)

Cinke, M., Li, J., Bauschlicher Jr, C. W., Ricca, A., Meyyappan, M., 2003, $CO_2$ adsorption in single-walled carbon nanotubes, Chem. Phys. Lett., 376, 761-766. crossref(new window)

Feng, B., An, H., Tan, E., 2007, Screening of $CO_2$ adsorbing materials for zero emission power generation systems, Energ. Fuel., 21, 426-434. crossref(new window)

IPCC, 2005, IPCC special report on carbon dioxide capture and storage, Cambridge University Press, New York, 105-178.

Jang, H. T., Park, Y. K., Ko, Y. S., Lee, J. Y., Margandan, B., 2009, Highly siliceous MCM-48 from rice hush ash for $CO_2$ adsorption, Int. J. Greenh. Gas Con., 3, 545-549 crossref(new window)

Lee, K. B., Beaver, M. G., Caram, H. S., Sircar, S., 2008, Reversible chemisorbents for carbon dioxide and their potential applications, Ind. Eng. Chem. Res., 47, 8048-8062. crossref(new window)

Lu, C., Su, F., Hsu, S. C., Chen, W., Bai, H., Hwang, J. F., Lee, H. H., 2009, Thermodynamics and regeneration of $CO_2$ adsorption on mesoporous spherical-silica particles., Fuel. Process. Tech., 90(12), 1543-1549. crossref(new window)

Siriwardane, R. V., Shen, M. S., Fisher, E. P., Poston, J. A., 2001, Adsorption of $CO_2$ on molecular sieves and activated carbon, Energ. Fuel., 15, 279-284. crossref(new window)

Su, F., Lu, C., Kuo, S. C., Zeng, W., 2010, Adsorption of $CO_2$ on amine-functionalized y-type zeolites, Energ. Fuel., 24(2), 1441-1448. crossref(new window)

Veawab, A., Tontiwachwuthikul, P., Chakma, A., 1999, Corrosion of carbon steel in the $CO_2$ absorption process using aqueous amine solutions, Ind. Eng. Chem. Res., 38, 3917-3924. crossref(new window)

Walton, K. S., Abney, M. B., Levan, M. D., 2006, $CO_2$ adsorption in Y and X zeolites modified by alkali metal cation exchange, Micropor. Mesopor. Mater., 91, 78-84. crossref(new window)

Wang, X. P., Jun, J. J., Cheng, J., Hao, Z. P., Xu, Z. P., 2008, High-temperature adsorption of carbon dioxide on mixed oxides derived from hydrotalcite-like compounds, Environ. Sci. Technol., 42, 614-618. crossref(new window)

Wei, J., Liao, J., Xiao, Y., Zhang, P., Shi, Y., 2010, Capture of carbon dioxide by amine-impregnated as-synthesized MCM41, J. Environ. Sci., 22(10), 1558-1563. crossref(new window)

Xu, X., Song, C., Andresen, J. M., Miller, B. G., Scaroni, A. W., 2003, Preparation and characterization of novel $CO_2$ "molecular basket" adsorbents based on polymer-modified mesoporous molecular sieve MCM41, Micropor. Mesopo. Mat., 62, 29-45. crossref(new window)