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Preparation of PVC-D2EHPA beads by Immobilization of D2EHPA on Polyvinyl Chloride as Solid Phase Extractant and Removal Characteristics of Cu(II)
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 Title & Authors
Preparation of PVC-D2EHPA beads by Immobilization of D2EHPA on Polyvinyl Chloride as Solid Phase Extractant and Removal Characteristics of Cu(II)
Kam, Sang-Kyu; You, Hae-Na; Lee, Dong-Hwan; Lee, Min-Gyu;
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The solid phase extractant (PVC-D2EHPA bead) was prepared by immobilizing di-2-ethylhexyl-phosphoric acid (D2EHPA) with polyvinyl chloride (PVC). The prepared PVC-D2EHPA beads were characterized by using fourier transform infrared spectrometer (FTIR) and scanning electron microscopy (SEM). The removal experiments of Cu(II) by PVC-D2EHPA beads conducted batchwise. The removal kinetics of Cu(II) was found to follow the pseudo-second-order model. The equilibrium data fitted well with Langmuir isotherm model and the maximum removal capacity was 2.6 mg/g at . The optimum pH region was in the range of 3.5 to 6. and the standard free energy () was between -4.67~-4.98 kJ/mol, indicating the spontaneous nature of Cu(II) removal by PVC-D2EHPA beads.
Di-2-ethylhexyl-phosphoric acid;Polyvinyl chloride;Solid phase extraction;Copper ion;
 Cited by
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