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Development of Analytical Method for Fenoxanil in Agricultural Products Using GC-NPD and GC/MS
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 Title & Authors
Development of Analytical Method for Fenoxanil in Agricultural Products Using GC-NPD and GC/MS
Kim, Gyeong-Ha; Ahn, Kyung-Geun; Kim, Gi-Ppeum; Hwang, Young-Sun; Lee, Young Deuk; Choung, Myoung-Gun;
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 Abstract
The aim of this study is to develop residue analysis method for fenoxanil, a MBI (melanin biosynthesis inhibitor) propionamide fungicide, had mainly been used to control rice blast, and disease of other crops, fruits, and vegetables by using GLC/NPD and GC/MS. Extraction with acetone and partition with n-hexane/dichloromethane (80/20, v/v) were performed from hulled rice, soybean, Kimchi cabbage, green pepper, and apple, then column clean-up with florisil was applied. Mean recoveries were 82.2%-109.1% with less than 7.2% of coefficients of variation and limit of quantitation was set at the concentration of 0.04 mg/kg from the five agricultural products through the determination by GLC/NPD equipped with DB-5 capillary column and single laboratory validation. As a confirmatory method, GC/MS selected ion monitoring (SIM) was set from m/z 125.0, 188.9, and 293.0. Developed method is expected to apply the single residue analysis of fenoxanil in agricultural products.
 Keywords
Fenoxanil;GC-NPD/MS;Single residue;
 Language
Korean
 Cited by
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