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The Measurement of Flash Point for Unflammable-Flammable Binary Mixtures(CCl4+o-Xylene and CCl4+p-Xylene) Using Open Cup Tester
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  • Journal title : Journal of Energy Engineering
  • Volume 24, Issue 4,  2015, pp.18-23
  • Publisher : The Korea Society for Energy Engineering
  • DOI : 10.5855/ENERGY.2015.24.4.018
 Title & Authors
The Measurement of Flash Point for Unflammable-Flammable Binary Mixtures(CCl4+o-Xylene and CCl4+p-Xylene) Using Open Cup Tester
Kim, Chang-Seob; Lee, Sungjin; Ha, Dong-Myeong;
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The flash point is used to categorize inflammable liquids according to their relative flammability. The flash point is important for the safe handling, storage, and transportation of inflammable liquids. The flash point temperature of two binary liquid mixtures( and ) has been measured for the entire concentration range using Tag open cup tester. The flash point temperature was estimated using Raoult`s law, UNIQUAC model and empirical equation. The experimentally derived flash point was also compared with the predicted flash point. The empirical equation is able to estimate the flash point fairly well for and mixture.
Tag open cup tester;flammable liquids;UNIQUAC model;binary liquid mixtures;
 Cited by
Phoon, L. Y., Mustaffa, A. A., Hashim, Mat, H. R. : "A Review of Flash Point Prediction Models for Flammable Liquid Mixtures", Ind. Eng. Chem. Res., Vol. 53, 12523-12565, (2014)

Crowl, D. A. and Louver, J. F.: "Chemical Process Safety Fundamentals with Applications", Prentice-Hall, (1990)

Lance, R. C., Barnard, A. J., Hooymanm, J. E. : "Measurement of Flash Points : Apparatus, Methodology, Applications", J. of Hazardous Materials, Vol. 3, 107-119, (1979) crossref(new window)

Affens, W. A. and Mclaren, G. W. : "Flammability Properties of Hydrocarbon Solutions in Air", J. of Chem. Ind. Eng. Chem., Vol. 17, No. 4, 482-488, (1972)

Chatelier, H. L. : "Estimation of Firedamp by Flammability Limits", Ann. Minmes, Vol. 19, No. 8, 388-395, (891)

Hanley, B. : "A Model for the Calculation and the Verification of Closed Cup Flash Points for Multicomponent Mixtures", Process Saf. Prog., Vol. 17, No. 2, 86-97, (1998) crossref(new window)

Poling, B. E., Prausnitz, J. M., O'Connell, J. P. : "The Properties of Gases and Liquids", 5th Ed., McGraw-Hill, New York, (2001)

Liaw, H. J., Lee, Y. H., Tang, C. L., Hsu H. H., Liu, J. H. : "A Mathematical Model for Predicting the Flash Point of Binary Solutions", J. of Loss Prevention in the Process Industries, Vol. 15, 429-438, (2002) crossref(new window)

Ha, D. M., Lee S. J., Back, M. H. : "The Measurement and Estimation of the Lower Flash Points for the Flammable Binary Systems Using Tag Open-Cup Tester", Korean J. Chem. Eng., Vol. 24, No. 4, 551-555, (2007) crossref(new window)

Wilson, G. M. : "Vapor Liquid Equilibrium. XI. A New Expression for the Excess Free Energy of Mixing", Journal of the American Chemical Society, Vol. 86, 127-130, (1964) crossref(new window)

Ha, D. M. and Lee, S. J. : "The Measurement of the Lower Flash Points for Binary Mixtures", J. of the Korean Society of Safety , Vol. 28, No. 1, 35-39, (2013)

In 2011 Annual Book of ASTM Standards ; ASTM International, : "Standard Test Methods for Flash Point of Liquids by Small Scale Closed-Cup Apparatus(ASTM D3278)", West Conshohocken, PA, (2011)

Gmehing, J., Onken U., Arlt, W. : "Vapor-Liquid Equilibrium Data Collection", Vol. 1, Part1-Part7, DECHEMA, (1980)

Lim, J., Jang, S., Kim, H., Cho, H. K., Shin, M. S. : "Solubility of Triclocarban in Pure Alkanols at Different Temperatures", Korean J. Chem. Eng., Vol. 30, No. 1, 181-186, (2013) crossref(new window)