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Particle Size, Morphology and Color Characteristics of C.I. Pigment Red 57:1 : 2. Effect of Salt Milling Process
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  • Journal title : Textile Coloration and Finishing
  • Volume 27, Issue 4,  2015, pp.245-260
  • Publisher : The Korean Society of Dyers and Finishers
  • DOI : 10.5764/TCF.2015.27.4.245
 Title & Authors
Particle Size, Morphology and Color Characteristics of C.I. Pigment Red 57:1 : 2. Effect of Salt Milling Process
Seo, Hee Sung; Lee, Hyun Kyung; Yoo, Eui Sang;
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The effect of salt milling process on the crystal size, morphology, and color characteristics of C.I. Pigment Red 57:1 was studied. The primitive morphology and color properties of the pigment after synthesis were studied in the former series work. The size and morphology of primary particles and the second aggregation features should be considered because they are very important to determine pigment quality. We compared the primary morphology of pigment particles before drying with the secondary aggregated morphology of pigment particles after drying and salt milling process. Morphological properties were investigated by particle size analysis, X-ray diffraction, and scanning electron microscopy and color measurement was carried out. Significant reduction in particle size as well as enhanced crystallite size after salt milling process was observed. This result might give a difference in color of the pigment, turning into brighter and more blue-toned red color. It was revealed that synthesis condition affect the morphology and color of the pigment even after milling. Increase in HCl concentration in the synthesis process enhanced crystal size and quality forming bluer-red pigments but an increase in concentration resulted in more amorphous crystals forming darker-red pigments after salt milling.
C.I. Pigment Red 57:1;salt milling process;crystal size;crystal morphology;color characteristics;
 Cited by
열전도성 입자를 활용한 시트용 점착제의 점착 특성과 방열특성 연구,김영수;박상하;최정우;공이성;윤관한;민병길;이승한;

한국염색가공학회지, 2016. vol.28. 1, pp.48-56 crossref(new window)
Comparative Analysis of Heat Sink and Adhesion Properties of Thermal Conductive Particles for Sheet Adhesive, Textile Coloration and Finishing, 2016, 28, 1, 48  crossref(new windwow)
V. A. Hackley and C. F. Ferraris, "The Use of Nomenclature in Dispersion Science and Technology", NIST, Washington, pp.4-30, 2001.

J. Kassel, Particle Dispersion for Size Analysis, J. of GXP Compliance, 15(3), 17(2011).

Toyo Ink Manufacturing Co. Ltd., U.S. Pat. 5776237 (1998).

The California Ink Co. Inc., U.S. Pat. 2982666 (1961).

H. Yungevis and E. Ozel, Effect of the Milling Process on the Properties of $CoFe_2O_4$ Pigment, Ceramics International, 39(5), 5503(2013). crossref(new window)

Bayer Corporation, E. I., DuPont De Nemours and Company, U.S. Pat. 6410619 B2(2002).

L. Pal and P. D. Fleming, The Study of Ink Pigment Dispersion Parameters, The Hilltop Review, J. of Western Michigan University Graduate Student Research, 2(1), 61(2006).

D. Shiota, Y. Tadokoro, K. Noda, M. Shida, and M. Fujii, Development of Low Reflectivity and High Resolution Negative-tone Photoresist, J. of Photopolymer Science and Technology, 24(4), 397(2011). crossref(new window)

Toray Industries Inc., U.S. Pat. 6455208 B1 (2002).

R. K. Harris, P. Jonsen, K. J. Packer, and C. D. Campbell, Investigation of the Structure of an Insoluble Pigment by Means of Nuclear Magnetic Resonance, J. of the Chemical Society, Perkin Transactions, 2(10), 1383(1987).

R. O. Loutfy and J. H. Sharp, Electrochemical and Spectroscopic Studies of Arylazo-2-naphthol Metal Complexes in Dimethylformamide Solution, J. of the American Chemical Society, 99(12), 4049(1977). crossref(new window)

G. R. Duckett, J. R. Fryer, and T. Baird, Electron Microscope Studies of a Mono-azo Pigment, Electron Microscopy and Analysis, Proceedings of the Institute of Physics Electron Microscopy and Analysis Group Conference Held at the University of Newcastle-upon-Tyne, 2-5 September 1985 (EMAG 85), Adam Hilger, Vol.78, p.437, 1985.

J. Clarkson, D. R. Armstrong, C. H. Munro, and W. E. Smith, Vibrational Analysis of the Phenylazonaphthol Pigment Ca4B, J. of Raman Spectroscopy, 29(5), 421(1998). crossref(new window)

Z. Hao and A. Iqbal, Some Aspects of Organic Pigments, Chemical Society Reviews, 26(3), 203 (1997). crossref(new window)

A. R. Kennedy, C. M. Nair, W. E. Smith, G. Chisholm, and S. J. Teat, The First Red Azo Lake Pigment whose Structure is Characterized by Single Crystal Diffraction, Angewandte Chemie International Edition, 39(3), 638(2000). crossref(new window)

R. M. Christie and J. L. Mackay, Metal Salt Azo Pigments, Coloration Technology, 124(3), 133(2008). crossref(new window)

S. L. Beko, S. M. Hammer, and M. U. Schmidt, Crystal Structures of the Hydration States of Pigment Red 57:1, Angewandte Chemie International Edition, 51(19), 4735(2012). crossref(new window)

W. Herbst and K. Hunger, "Industrial Organic Pigments: Production, Properties, Applications, 3rd ed.", Wiley-VCH, Weinheim, p.44, 2004.

H. Zollinger, "Color Chemistry: Synthesis, Properties and Applications of Organic Dyes and Pigments, 2nd ed.", VCH, Weinheim, p.182, pp.100-127, p.296, 1991.

R. M. Christie and S. Moss, Metal Salt Azo Pigments Derived from 3-hydroxy-2-naphthohydroxamic Acid, Dyes and Pigments, 8(3), 211(1987). crossref(new window)

I. M. Arabatzis, S. Antonaraki, T. Stergiopoulos, A. Hiskia, and E. Papaconstantinou, Preparation, Characterization and Photocatalytic Activity of Nanocrystalline Thin Film $TiO_2$ Catalysts towards 3,5-dichlorophenol Degradation, J. of Photochemistry and Photobiology A: Chemistry, 149(1-3), 237(2002). crossref(new window)

R. W. G. Hunt and M. R. Pointer, "Measuring Colour, 4th ed.", John Wiley and Sons, Ltd., UK, p.57, 2011.

N. M. Deraz and A. Alarifi, Structural, Morphological and Magnetic Properties of Nanocrystalline Zinc Substituted Cobalt Ferrite System, J. of Analytical and Applied Pyrolysis, 94, 41(2012). crossref(new window)

B. D. Cullity, "Elements of X-ray Diffraction, 2nd ed.", Addison-Wesley, USA, p.99, 1990.

The Supplementary Crystallographic Data for this Paper are Available from The Cambridge Crystallographic Data Centre via(CCDC 851322; $C_{18}H_{12}$ $CaN_2O_6S{\cdot}3H_2O$, Mr=478.49, monoclinic, $P_{21}/c$, a=8.7613(5)${\AA}$, b=5.8155(3)${\AA}$, c=37.943(2)${\AA}$, ${\beta}=90.883(3)^{\circ}$, V=1933.03(18)${\AA}$, Z=4, ${\rho}_{calc}=1.644gcm^{-3}$, $CuKa_1$ radiation(${\lambda}=1.5406{\AA}$), $2{\theta}=2-80^{\circ}$, Measured at Ambient Temperature, Available at, 2015.10.01.

J. Lee, T. Isobe, and M. Senna, Preparation of Ultrafine $Fe_3O_4$ Particles by Precipitation in the Presence of PVA at High pH, J. of Colloid and Interface Science, 177(2), 490(1996). crossref(new window)

W. H. Hall, X-ray Line Broadening in Metals, Proceedings of the Physical Society: Section A, London, Vol.62, No.11, p.741, 1949.

A. J. Maisano, Cryomilling of Aluminum-based and Magnesium-based Metal Powders, M.S. Thesis, Virginia Polytechnic Institute and State University, 2006.

R. R. Mather, The Degree of Crystal Aggregation in Organic Pigments, Dyes and Pigments, 42(1), 103(1999). crossref(new window)

E. N. Oparah, Synthesis of Acid Azo Dyes based on 6-amino-1-naphthol-3-sulphonic Acid and the Assessment of their Properties on Nylon, Wool and Leather, Ph.D. Thesis, Ahmadu Bello University, 2010.

M. Quinten, The Color of Finely Dispersed Nanoparticles, Applied Physics B: Lasers and Optics, 73(4), 317(2001). crossref(new window)

K. S. L. Corre, E. V. Jones, P. Hobbs, and S. A. Parsons, Impact of Calcium on Struvite Crystal Size, Shape and Purity, J. of Crystal Growth, 283 (3), 514(2005). crossref(new window)

H. H. Ko, G. Yang, H. Z. Cheng, M. C. Wang, and X. J. Zhao, Growth and Optical Properties of Cerium Dioxide Nanocrystallites Prepared by Coprecipitation Routes, Ceramics International, 40(3), 4055(2014). crossref(new window)

J. J. Joshi, D. B. Vaidya, and H. S. Shah, Application of Multi-flux Theory based on Mie Scattering to the Problem of Modeling the Optical Characteristics of Colored Pigmented Paint Films, Color Research and Application, 26(3), 234(2001). crossref(new window)

C. F. Bohren and D. R. Huffman, "Absorption and Scattering of Light by Small Particles", Wiley-VCH, Weinheim, pp.8-9, 2004.

C. S. Roesler, S. M. Etheridge, and G. C. Pitcher, Application of an Ocean Color Algal Taxa Detection Model to Red Tides in the Southern Benguela, Proceedings of the Xth International Conference on Harmful Algae, Florida Fish and Wildlife Conservation Commission and Intergovernmental Oceanographic Commission of UNESCO, St. Petersburg Beach, Florida, USA, p.303, 2003.

F. Xuening, Z. Tianyong, and Z. Chunlong, Modification Study Involving a Naphthol as Red Pigment, Dyes and Pigments, 44(2), 75(2000). crossref(new window)

J. S. Bae, S. Y. Gwon, and S. H. Kim, Anthraquinone- carbamodithiolate Assembly as Selective Chromogenic Chemosensor for $Fe^{3+}$, Textile Coloration and Finishing, 25(1), 13(2013). crossref(new window)

H. Kim, X. Li, and Y. A. Son, Electrochemical Study on Energy Potential Levels with Pyrene Molecule, Textile Coloration and Finishing, 25(3), 159(2013). crossref(new window)

L. Chromy and E. Kaminska, Relationship between the Optical Properties of Coloured Pigments and their Morphology and Crystalline Structure, Progress in Organic Coatings, 6(1), 31(1978). crossref(new window)

M. Quinten, Optical Effects Associated with Aggregates of Clusters, J. of Cluster Science, 10(2), 319(1999). crossref(new window)

J. Turkevich, Colloidal Gold, Part II, Gold Bulletin, 18(4), 125(1985). crossref(new window)