Publisher : The Korean Society of Dyers and Finishers
DOI : 10.5764/TCF.2016.28.2.70
Title & Authors
Attachment of Silver Nanoparticles to the Wool Fiber Using Glycidyltrimethylammonium Chloride(GTAC) Lee, Seungyoung; Sul, In Hwan; Lee, Jaewoong;
Silver nanoparticles(AgNPs) were attached to wool fibers using glycidyltrimethylammonium chloride(GTAC), which is a type of quaternary ammonium salt. GTAC, which contains an epoxy functional group that, under high temperatures, generates a ring-opening reaction with wool fibers, which contain the amine group. Then, the AgNPs are attached to the surface of the GTAC-treated wool fibers by treatment with a silver colloidal solution. The process involves the following procedures: (1) The wool fibers are immersed in the GTAC solution, followed by pre-drying at and curing at to induce an alteration in the chemical structure; and (2) The wool fibers treated with GTAC are immersed in the silver colloid at for 120 min to chemically induce a strong attachment of the AgNPs to the wool fibers. Scanning electron microscopy was used to analyze the influence of the concentrations of GTAC and the silver colloid, as well as the influence of the applied temperature of the silver colloid on the wool fibers, and the influence of the morphological changes in the wool fiber surfaces. As a result, the enhanced concentrations of GTAC and the silver colloid together with an elevated applied temperature of silver colloid have a tendency to increase in Ag atomic%.
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