Publisher : The Korean Institute of Surface Engineering
DOI : 10.5695/JKISE.2011.44.5.185
Title & Authors
Cu2ZnSnSe4 Thin Films Preparation by Pulsed Laser Deposition Using Powder Compacted Target Kim, Kyoo-Ho; Wibowo, Rachmat Adhi; Alfaruqi, M.Hilmy; Ahn, Jong-Heon;
thin films for solar absorber application were prepared by pulsed laser deposition of a synthesized compound target. The film's composition revealed that the deposited films possess an identical composition with the target material. Further film compositional control toward a stoichiometric composition was performed by optimizing substrate temperature, deposition time and target rotational speed. At the optimum condition, X-ray diffraction patterns of films showed that the films demonstrated polycrystalline stannite single phase with a high degree of (112) preferred orientation. The absorption coefficient of thin films were above 104 cm.1 with a band gap of 1.45 eV. At an optimum condition, films were identified as a p type semiconductor characteristic with a resistivity as low as and a carrier concentration in the order of .
S. H. Wei, S. B. Zhang, A. Zunger, Appl. Lett. Phys., 72 (1998) 3199.
P. D. Paulson, H. M. Haimbodi, S. Marsillac, R. W. Birkmire, W. N. Shafarman, J. Appl. Phys., 91 (2002) 10153.
S. Marsillac, P. D. Paulson, M. W. Haimbodi, R. W. Birkmire, W. N. Shafarman, Appl. Phys. Lett., 81 (2002) 1350.
H. Katagiri, Thin Solid Films 480-481 (2005) 426.
V. F. Gremenok, E. P. Zaretskaya, V. M. Siarheyeva, K. Bente, W. Scmitz, V. B. Zalesski, H. J. Moller, Thin Solid Films, 487 (2005) 193.
H. Matsushita, T. Maeda, A. Kasui, T. Takazawa, J. Cryst. Growth., 208 (2000) 416.
I. D. Olekseyuk, L. D. Gulay, I. V. Dydchak, L. V. Piskach, O. V. Parasyuk, O. V. Marchuk, J. Alloys and Comp., 340 (2002) 141.
T. M. Friedlmeier, H. Dittrich, H. W. Schock, 11th Conference on Ternary and Multinary Compounds, ICTMC-11, Salford, 8-12 September 1997, (1997) 345.
R. A. Wibowo, W. S. Kim, E. S. Lee, B. Munir, K. H. Kim, J. Phys. Chem. Solid, 68 (2007) 1908.
R. A. Wibowo, E. S. Lee, B. Munir, K. H. Kim, Phys. Stat. Sol. A, 204 (2007) 7737.
E. Mellikov, D. Meissner, T. Varema, M. Altosaar, M. Kauk, O. Volobujeva, J. Raudoja, K. Timmo, M. Danilson, Sol. Energy Mater. Sol. Cells, 93 (2009) 65.
I. W. Boyd, Ceram. Int., 21 (1996) 429.
V. F. Gremenok, R. W. Martin, I. V. Bodnar, M. V. Yakushev, W. Schmitz, K. Bente, I. Martil, F. L. Martinez, E. P. Zaretskaya, I. A. Victorov, O. V. Ermakov, C. A. Faunce, R. D. Pilkington, A. E. Hill, R. D. Tomlinson, Thin Solid Films, 394 (2001) 24.
S. Kuranouchi, A. Yoshida, Thin Solid Films, 343-344 (1999) 123.
P. Victor, J. Nagaraju, S. B. Krupanindhi, Solid State. Comm., 116 (2000) 649.
D. B. Chrisey, G. K. Hubler, Pulsed Laser Deposition of Thin Films, John Wiley and Sons, Inc., New York (1994) 14.
D. Zhang, L. Guan, Z. Li, G. Pan, X. Tan, L. Li, Appl. Surf. Sci., 253 (2006) 874.