JOURNAL BROWSE
Search
Advanced SearchSearch Tips
Formation of Zn(II) Complexes of Physiological Buffer Amino alcohols in Aqueous Solution
facebook(new window)  Pirnt(new window) E-mail(new window) Excel Download
 Title & Authors
Formation of Zn(II) Complexes of Physiological Buffer Amino alcohols in Aqueous Solution
Hong, Kyung-Hee; Chun, Yong-Jin;
  PDF(new window)
 Abstract
The complex formation from Zn(II) ion and 2-(2-hydroxyethylamino)-2-(hydroxymethyl)-1,3-propanediol (Monotris), Bis(2-hydroxyethyl)imino-tris(hydroxymethyl)methane(Bistris) in aqueous solution at and at an ionic strength of 0.10 M have been studied potentiometrically. For the Zn(II)-Monotris system, in the Monotris (L) complex , one of the hydroxyl oxygen atoms as well as the amine nitrogen of the ligand are coordinated. In basic media, the coordinated hydroxyl group is deprotonated. For the Zn(II)-Bistris system, in the Bistris(L) complex , two of the hydroxyl oxygen atoms as well as the amine nitrogen of the ligand are coordinated. In basic media, one of the coordinated hydroxyl groups is deprotonated. In very high basic media, an additional hydroxyl group undergoes deprotonation. The equilibrium constants for the formation of , , , and have been determined.
 Keywords
Bistris;deprotonation;Monotris;potentiometry;equilibrium constant;
 Language
Korean
 Cited by
 References
1.
J. C. Lewis, "Mono- and "Mono-tris"and "Bis-tris", Anal. Biochem., 14, 495, 1966. DOI: http://dx.doi.org/10.1016/0003-2697(66)90294-6 crossref(new window)

2.
T. Laureys, I. S. S. Pinto, C. V. M. Soares, H. B. Boppudi, H. M. V. Soares, "Complexation of 1,3-bis(tris(hydroxymethyl)methylamino)propane Systems Involving Divalent Ions in Aqueous Solutions by Potentiometry", J. Chem. Eng. Data, 57, 87, 2012. DOI: http://dx.doi.org/10.1021/je200809m crossref(new window)

3.
C. M. H. Ferreira, I. S. S. Pinto, G. M. S. Alves, S. M. Sedeghi, H. M. V. M. Soares. "Aqueous complexation studies of lead(II) and cadmium(II) with 1,3-bis(tris(hydroxymethyl)methyl amino)propane pH buffer", J. Coord. Chem., 67, 20, 2014. DOI: http://dx.doi.org/10.1080/00958972.2014.908188

4.
Y. Ito, N. Satoh, T. Ishii, J. Kumakura, T. Hirano, "Development of a homogeneous assay for measurement of high-density lipoprotein-subclass cholesterol", Cli. Chim. Acta., 427, 86, 2014. DOI: http://dx.doi.org/10.1016/j.cca.2013.09.009 crossref(new window)

5.
S. M. Sadbghi, C. M. H. Ferreira, S. Vandenbogaerde, H. M. V. M. Soares, "Graphical data anslysis and complex formation curves as modeling and optimization tools for characterization of Cu-(buffer)x-(OH)y systems involving BTP or BES in aqueous solution", J. Coord. Chem., 68, 5, 777, 2015. crossref(new window)

6.
Helmut Sigel and Rolf Griessera, "Nucleoside 5' -triphosphates: self-association, acid-base, and metal ion-binding properties in solution", Chem. Soc. Rev., 34, 875, 2005. DOI: http://dx.doi.org/10.1039/b505986k crossref(new window)

7.
A. Persat, R. D. Chambersa, J. G. Santiago, "Basic principles of electrolyte chemistry for micro fluidic electrokinetics. Part I: Acid-base equilibria and pH buffers", Lab. Chip., 9, 2437, 2009. DOI: http://dx.doi.org/10.1039/b906465f crossref(new window)

8.
Zdena Hala, Petr Gebauer and Petr Bocek, "Recent progress in analytical capillary isotacho phoresis", ELECTROPHORESIS, 36, 2, 2015. DOI: http://dx.doi.org/10.1002/elps.201400337 crossref(new window)

9.
F. I. Rosell, M. R. Mauk, and A. G Mauk, "pH and Metal Ion-Linked Stability of the Hemopexin-Heme Complex", Biochemistry, 44, 6, 1872, 2005. crossref(new window)

10.
S. J. Oh, Y. S. Choi, S. H. S. C. Bae, J. K. Ku and J. W. Park, "Structure and phosphodiesterase activity of Bis-Tris coordinated lanthanide(III) complexes", Chem. Commun., 2189, 1998. DOI: http://dx.doi.org/10.1039/a806021e

11.
Mohamed Tahaa and Ming-Jer Lee, "Interactions of TRIS [tris(hydroxymethyl)aminomethane] and related buffers with peptide backbone Thermodynamic characterization", Phys. Chem., 12, 12840, 2010. DOI: http://dx.doi.org/10.1039/c0cp00253d

12.
K. H. Hong, S. B. Shim, Y. J. Chun, "Copper(II) Complexation by 2-(2-Hydroxyethylamino)-2- (hydroxymethyl)-1,3propanediol in Aqueous Solution", CCIS, 338, 69, 2012.

13.
K. H. Hong, S. B. Shim, S. G. Oh, Y. J. Chun, "A Study on the Complexation of Nickel ion with 2-(2-Hydroxyethylamino)-2-(hydroxymethyl)-1,3 -propanediol in Aqueous Solution", Journal of Korea Academia-Industrial cooperation Society, 12, 11, 5221, 2010. DOI: http://dx.doi.org/10.5762/KAIS.2010.11.12.5221

14.
K. H. Hong, E. J. Ha, K. S. Bai, "A Study on the Complexation of Copper(II) Ion with 2,2-Bis (hydroxymethyl)-2.2',2''-nitrilotriethanol in Aqueous Solution", Bull. Kor. Chem. Soc.,16, 406, 1995.

15.
H. S. Harned, B. B. Owen, "The Physical Chemistry of ELETROLYTIC SOLUTIONS", Seond Edition, Reinhold Publishing Corporation, 37, 1950.

16.
R. F. Jameson, M. F. Wilson, J. Chem. Soc. Dalton Trans., 2607, 1972. DOI: http://dx.doi.org/10.1039/dt9720002607

17.
A. E. Martell, R. M. Motekaitis, "Determination and Use of Stability Constants", VCH publishers Inc. 1992.

18.
Joan Ribas Gispert, "Coordination Chemistry", Wiley-VCH Verlag Gmbh & Co. KGaA, Weinheim, 64, 2008.

19.
F. M. Al-Sogair, B. P. Operschall, A. Sigel, H. Sigel, J. Schnabl, R. K. O. Sigel, "Probing the Metal-Ion Binding Strength of Hydroxyl Group", Chem. rev., 111, 4964, 2011. DOI: http://dx.doi.org/10.1021/cr100415s crossref(new window)

20.
R. M. Smith, A. E. Martell, "Critical Stability Constants", Vol.2, Amines, 1975; Vol.5, First Suppl., 1982; and Vol.6, Second Suppl., 1989; Plenum press: New York, N. Y. DOI: http://dx.doi.org/10.1007/978-1-4615-6764-6

21.
K. H. Hong, K. S. Bai, "Formation of Ni(II) Complexes of BTP in Aqueous solution", Bull. Korean Chem. Soc., 21, 6, 650, 2000.

22.
S. Kotila, J. Valkonen, "Copper(II) Complexes of 2-amino-2-hydroxymethyl-1,3-propanediol. Part 3. synthesis. Structure and Thermal Behavior of Bis-cis[2-amino-2-hydroxymethyl-1,3-propanediola diolate-O,N]aquocopper(II) Sulfate and Chromate, [Cu(C4H10NO3)(C4H11NO3)(H2O)]2X, where X=SO42-, CrO42-", Acta. Chem. Scan., 48, 200, 1994. DOI: http://dx.doi.org/10.3891/acta.chem.scand.48-0312 crossref(new window)

23.
S. Kotila, J. Valkonen, "Copper(II) Complexes of cis[2-amino-2-hydroxymethyl-1,3-propanediolato- O,N]copper(II) Potassium Fluoride and Bromide [Cu(C4H10NO3)2]KF.3H2O. [Cu(C4H10NO3)2] KBr.2H2O", Acta. Chem. Scan., 48, 312, 1994. DOI: http://dx.doi.org/10.3891/acta.chem.scand.48-0200 crossref(new window)

24.
Y. Inomata, Y. Gochou, M. Nogami, F. S. Howell, T. Takeuchi, "Characterization of ternary bivalent metal complexes with bis(2-hydroxyethyl)iminotris (hydroxymethy)methane(Bis-Tris) and the comparison of five crystal structures of Bis- Tris complexes", Journal of Molecular Structure, 702, 61, 2004. DOI: http://dx.doi.org/10.1016/j.molstruc.2004.06.010 crossref(new window)

25.
T. C. Stamatatos, K. A. Abbouda, G. Christou, "A mononuclear MnIII/'bis-tris' complex and its conversion to a mixed-valence MnII/III5cluster", Dalton Trans., 41, 2009. DOI: http://dx.doi.org/10.1039/B810701G crossref(new window)

26.
Z. Heren, H. Pasaoglu, G. Kastas and K. Akdag, "Spectrothermal and Structural Characterization of Saccharinatobis(tris-hydroxymethylamino methane) Zinc(II)saccharinate Complex,[Zn(sac)(tham)2](sac)", Z. Anorg. Allg. Chem., 634, 933, 2008. DOI: http://dx.doi.org/10.1002/zaac.200800201

27.
G. J. M. Ivarsson, "Structure of bis[tris(hydroxy methyl)aminomethane]nickel(II)diperchlorate", Acta. Crystallgr., B38, 1828, 1982. DOI: http://dx.doi.org/10.1107/S0567740882007341