JOURNAL BROWSE
Search
Advanced SearchSearch Tips
Study on Polyhydroxyamide/Carbon Nanotube Nanocomposite Fibers
facebook(new window)  Pirnt(new window) E-mail(new window) Excel Download
  • Journal title : Textile Science and Engineering
  • Volume 52, Issue 6,  2015, pp.361-366
  • Publisher : The Korean Fiber Society
  • DOI : 10.12772/TSE.2015.52.361
 Title & Authors
Study on Polyhydroxyamide/Carbon Nanotube Nanocomposite Fibers
Jee, Min Ho; Kang, Chan Sol; Yeo, Moon Jin; Baik, Doo Hyun;
  PDF(new window)
 Abstract
Polyhydroxyamide (PHA) was synthesized by low-temperature solution polymerization of 3,3`-dihydroxybenzidine and terephthaloyl chloride. Then, pure PHA and PHA nanocomposite fibers, including multi-walled carbon nanotube (MWNT), were prepared by a wet-spinning process. The structural characteristics, thermal properties, and mechanical performances, such as tensile strength, initial modulus, and compressive strength, of the PHA fibers were investigated using FT-IR, TGA, and a tensile testing machine. The TGA results show that the PHA fiber has excellent thermal stability at high temperatures and can undergo thermal cyclization to yield PBO fiber. The tensile mechanical properties of PHA nanocomposite fibers were better than those of pure PHA fiber, and they were improved on increasing the MWNT content. The highly improved mechanical properties of the nanocomposite fibers are thought to be related to the strong interfacial interactions between the PHA matrix and MWNT.
 Keywords
polyhydroxyamide fiber;multi-walled carbon nanotube;wet-spinning;mechanical properties;
 Language
Korean
 Cited by
1.
Thermal Cyclization Behavior of Polyhydroxyamide Copolymers, Textile Science and Engineering, 2016, 53, 5, 340  crossref(new windwow)
 References
1.
C. Gao and S. W. Kantor, "Synthesis of Precursor Flame Suppressing Polymers", 54th eds., Spring SPE Meeting in Indianapolis in May, 1996, 3, 3072-3073.

2.
H. Hsiao and C. H. Yu, "Aromatic Polybenzoxazoles Bearing Ether and Isopropylidene or Hexafluoroisopropylidene Units in the Main Chain", Macromol. Chem. Phys., 1998, 199, 1247-1253. crossref(new window)

3.
H. Zhang, R. J. Farris, and P. R. Westmoreland, "Low Flammability and Decomposition Behavior of Poly(3,3'-dihydroxybiphenyl isophthalamide) and Its Derivatives", Macromolecules, 2003, 36, 3944-3954. crossref(new window)

4.
S. H. Hsiao and L. R. Dai, "Synthesis and Properties of Novel Aromatic Poly(o-hydroxyamide)s and Polybenzoxazoles Based on the Bis(ether benzoyl chloride)s from Hydroquinone and Its Methyl-tert-Butyl-, and Phenyl-Substituted Derivatives", J. Polym. Sci. Part A: Polym. Chem., 1999, 37, 2129-2136.

5.
D. H. Baik, E. K. Kim, and M. K. Kim, "Praparation of New Heat-resistant Fiber Materials Using Polymeric Precursors to Polybenzoxazoles(I)-Synthesis and Thermal Cyclization of PHA Derivatives-", J. Korean Fiber Soc., 2003, 40, 13-19.

6.
M. H. Jee, M. J. Paik, C. S. Kang, and D. H. Baik, "Synthesis and Thermal Cyclization of Aromatic Polyhydroxyamides(II) -Effect of Fluoro-substituents-", Text. Sci. Eng., 2013, 50, 308-314. crossref(new window)

7.
D. H. Baik, H. Y. Kim, and S. W. Kantor, "Synthesis and Cyclization of Aromatic Polyhydroxyamides Containing Trifluoromethyl Groups", Fiber. Polym., 2002, 3, 91-96. crossref(new window)

8.
C. S. Kang, M. J. Paik, C. W. Park, and D. H. Baik, "Synthesis and Characterization of Polyhydroxyamide Copolymer as Precursors of Polybenzoxazoles", Fiber. Polym., 2015, 16, 239-244. crossref(new window)

9.
S. K. Park, S. H. Cho, and R. J. Farris, "Dry-jet Wet Spinning of Polyhydroxyamide Fibers", Fiber. Polym., 2000, 1, 92-96. crossref(new window)

10.
H. Wang and T. S. Chung, "The Evolution of Physicochemical and Gas Transport Properties of Thermally Rearranged Polyhdroxyamide (PHA)", J. Membr. Sci., 2011, 385-386, 86-95. crossref(new window)

11.
S. L. C. Hsu and W. C. Chen, "A Novel Positive Photosensitive Polybenzoxazole Precursor for Microelectronic Applications", Polymer, 2002, 43, 6746-6750.

12.
G. M. Wu and C. H. Hung, "Mechanical Properties and Thermogravimetric Analysis of PBO Thin Films", J. Ach. Mater. Manufac. Eng., 2006, 17, 27-32.

13.
S. Bourbigot, X. Flambard, and F. Poutch, "Study of the Thermal Degradation of High Performance Fibres-Application to Polybenzoxazole and p-Aramid Fibres", Polym. Degrad. Stab., 2001, 74, 283-290. crossref(new window)

14.
C. S. Kang, M. H. Jee, and D. H. Baik, "Effect of Wet-Spinning and Heat-Treatment on the Structure and Mechanical Properties of Polyhydroxyamide Fibers(I)-Coagulation Behavior at Various Coagulation Conditions", Text. Sci. Eng., 2013, 50, 217-224. crossref(new window)

15.
M. H. Jee, J. Y. Lee, and D. H. Baik, "Synthesis and Thermal Cyclization of Aromatic Polyhdroxuamies(I)-Effect of the Benzene Ring Substitution Structure-", Text. Sci. Eng., 2012, 49, 324-330. crossref(new window)

16.
T. Zhang, J. Jin, S. Yang, G. Li, and J. Jiang, "A Rigid-rod Dihydroxy Poly(p-phenylene benzobisoxazole) Fiber with Improved Compressive Strength", Carbohydr. Polym., 2009, 78, 364-366. crossref(new window)

17.
A. Leal, J. M. Deitzel, and J. W. Gillespie, "Compressive Strength Analysis for High Performance Fibers with Different Modulus in Tension and Compression", J. Compos. Mater., 2009, 43, 661-674. crossref(new window)

18.
G. H. Jang, B. G. Min, Y. G. Jeong, and K. H. Yoon, "Improved Compressive Strength of Poly(p-phenylene benzobisoxazole) Copolymer Fiber Containing Multi-functional Comonomer", Fiber. Polym., 2014, 15, 895-898. crossref(new window)

19.
S. Kumar, T. D. Dang, F. E. Arnold, A. R. Bhattacharyya, B. G. Min, X. Zhang, R. A. Vaia, C. Park, W. W. Adams, R. H. Hauge, R. E. Smalley, S. Ramesh, and P. A. Willis, "Synthesis, Structure, and Properties of PBO/SWNT Composites", Macromolecules, 2002, 35, 9039-9043. crossref(new window)