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Boron removal from model water by RO and NF membranes characterized using S-K model
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  • Journal title : Membrane Water Treatment
  • Volume 7, Issue 3,  2016, pp.193-207
  • Publisher : Techno-Press
  • DOI : 10.12989/mwt.2016.7.3.193
 Title & Authors
Boron removal from model water by RO and NF membranes characterized using S-K model
Kheriji, Jamel; Tabassi, Dorra; Bejaoui, Imen; Hamrouni, Bechir;
Boron is one of the most problematic inorganic pollutants and is difficult to remove in water. Strict standards have been imposed for boron content in water because of their high toxicity at high concentrations. Technologies using membrane processes such as reverse osmosis (RO) and nanofiltration (NF) have increasingly been employed in many industrial sectors. In this work, removal of boron from model water solutions was investigated using polyamide reverse osmosis and nanofiltration membranes. RO-AG, RO-SG, NF-90 and NF-HL membranes were used to reduce the boron from model water at different operational conditions. To understand the boron separation properties a characterization of the four membranes was performed by determining the pure water permeability, surface charge and molecular weight cut-off. Thereafter, the effect of feed pressure, concentration, ionic strength, nature of ions in solution and pH on the rejection of boron were studied. The rejection of boron can reach up to 90% for the three membranes AG, SG and NF-90 at pH
boron;RO/NF membrane;Spiegler-Kedem model;mass transfer;
 Cited by
Bellona, C. and Drewes, J.E. (2005), "The role of membrane surface charge and solute physico-chemical properties in the rejection of organic acids by NF membranes", J. Membr. Sci., 249(1-2), 227-234. crossref(new window)

Cengeloglu, Y., Arslan, G., Tor, A. and Dursun, I. (2008), "Removal of boron from water by using reverse osmosis", Separ. Purif. Technol., 64(2), 141-146. crossref(new window)

Choi, J.H., Fukushi, K. and Yamamoto, K. (2008), "A study on the removal of organics acids from wastewater using nanofiltration membranes", Separ. Purif. Technol., 59(1), 17-25. crossref(new window)

Demetrioua, A., Pashalidisa I., Nicolaides, A.V. and Kumkeb, M.U. (2013), "Surface mechanism of the boron adsorption on alumina in aqueous solutions", Desal. Water Treat., 51(31-33), 6130-6136. crossref(new window)

Drinking-water Standards for New Zealand (Revised 2008) (2005), Wellington: Ministry of Health, Water Quality Standards, 8 p.

Dydo, P. and Turek, M. (2013), "Boron transport and removal using ion-exchange membranes: A critical review", Desalination, 310, 2-8. crossref(new window)

Essington, M.E. (2004), Soil and Water Chemistry: An Integrative Approach, CRC Press, Boca Raton, FL, USA.

Huertas, E., Herzberg, M., Oron, G. and Elimelech, M. (2008), "Influence of biofouling on boron removal by nanofiltration and reverse osmosis membranes", J. Membr. Sci., 318(1-2), 264-270. crossref(new window)

Irawan, C., Kuo, Y. and Liu, J.C. (2011), "Treatment of boron-containing optoelectronic wastewater by precipitation process", Desalination, 280(1-3), 146-151. crossref(new window)

Jain, S. and Gupta, S.K. (2004), "Analysis of modified surface force pore flow model with concentration polarization and comparison with Spiegler-Kedem model in reverse osmosis systems", J. Membr. Sci., 232(1-2), 45-61. crossref(new window)

Kabay, N., Yelmaz, I., Yamac, S., Yuksel, M., Yuksel, U., Yildirim, N., Aydogdu, O., Iwanaga, T. and Hirowatari, K. (2004), "Removal and recovery of boron from geothermal wastewater by selective ionexchange resins-II. Field tests", Desalination, 167, 427-438. crossref(new window)

Kha, L.T., Nghiema, L.D. and Allan, C.R. (2011), "Coupling effects of feed solution pH and ionic strength on the rejection of boron by NF/RO membranes", Chem. Eng. J., 168(2), 700-706. crossref(new window)

Koseoglu, H., Kabay, N., Yuksel, M. and Kitis, M. (2008), "The removal of boron from model solutions and seawater using reverse osmosis membranes", Desalination, 223(1-3), 126-133. crossref(new window)

Krieg, H.M., Modise, S.J., Keizer, K. and Neomagus, H.W.J.P. (2004), "Salt rejection in nanofiltration for single and binary salt mixtures in view of sulfates removal", Desalination, 171(2), 205-215.

Loizou, E., Kanari, P.N., Kyriacou, G. and Aletrari, M. (2010), "Boron determination in a multi element national water monitoring program: the absence of legal limits", J. Consum. Protect. Food Safe., 5(3), 459-463. crossref(new window)

Maung, H.O. and Lianfa, S. (2009), "Effect of pH and ionic strength on boron removal by RO membranes", Desalination, 246(1-3), 605-612. crossref(new window)

Mel'nik, L.A., Butnik, I.A. and Goncharuk, V.V. (2008), "Sorption-membrane removal of boron compounds from natural and waste waters: Ecological and economic aspects", J. Water Chem. Technol., 30(3), 167-179. crossref(new window)

Missaoui, K., Bouguerra, W., Hannechi, C. and Hamrouni, B. (2013), "Boron removal by electrocoagulation using full factorial design", J. Water Res. Protect., 5(9), 867-875. crossref(new window)

Mnif, A., Ben Sik Ali, M. and Hamrouni, B. (2010), "Effect of some physical and chemical parameters on fluoride removal by nanofiltration", Ionics, 16(3), 245-253. crossref(new window)

Morisada, S., Rin, T., Ogata, T., Kim, Y. and Nakano, Y. (2011), "Adsorption removal of boron in aqueous solutions by amine-modified tannin gel", Water Research, 45(13), 4028-4034. crossref(new window)

Nagasawa, H., Lizuka, A., Yamasaki, A. and Yanagisawa, Y. (2011), "Utilization of bipolar membrane electrodialysis for the removal of boron from aqueous solution", Ind. Eng. Chem. Res., 50(10), 6325-6330. crossref(new window)

Norberg, D., Hong, S., Taylor, J. and Zaho, Y. (2007), "Surface characterization and performance evaluation of commercial fouling resistant low-pressure RO membranes", Desalination, 202 (1-3), 45-52. crossref(new window)

Prats, D., Chillon-Arias, M.F. and Pastor, R.M. (2000), "Analysis of the influence of pH and pressure on the elimination of boron in reverse osmosis", Desalination, 128(3), 269-273. crossref(new window)

Redondo, J., Busch, M. and De Witte, J.P. (2003), "Boron removal from seawater using FILMTECTM high rejection SWRO membranes", Desalination, 156(1-3), 229-238. crossref(new window)

Rodriguez, P.M., Ferrandiz, R.M., Chillon, F. and Prats, R.D. (2001), "Influence of pH in the elimination of boron by means of reverse osmosis", Desalination, 140(2), 145-152. crossref(new window)

Sassi, K.M. and Mujtaba, I.M. (2013), "MINLP based superstructure optimization for boron removal during desalination by reverse osmosis", J. Membr. Sci., 440, 29-39. crossref(new window)

Schaep, J., Vandescasteele, C., Wahab, M.A. and Richard, B.W. (2001), "Modelling the retention of ionic components for different nanofiltration membranes", Separ. Purif. Technol., 22-23, 169-179. crossref(new window)

Schafer, A.I., Pihlajamaki, A., Fane, A.G., Waite, T.D. and Nystrome, M. (2004), "Natural organic matter removal by nanofiltration: effects of solution chemistry on retention of low molar mass acids versus bulk organic matter", J. Membr. Sci., 242(1-2), 73-85. crossref(new window)

Shim, Y., Lee, H.-G., Lee, S., Moon, S.H. and Cho, J. (2002), "Effects of NOM and ionic species on membrane surface charge", Environ. Sci. Technol., 36(17), 3864-3871. crossref(new window)

Szymczyk, A. and Fievet, P. (2006), "Ion transport through nanofiltration membranes: the steric, electric and dielectric exclusion model", Desalination, 200(1-3), 122-124. crossref(new window)

Tabassi, D., Mnif, A. and Hamrouni, B. (2013), "Influence of operating conditions on the retention of phenol in water by reverse osmosis SG membrane characterized using Spiegler-Kedem model, Separ. Purif. Technol., 52(7-9), 1792-1803.

Tomaszewska, B. and Bodzek, M. (2013), "Desalination of geothermal waters using a hybrid UF-RO process, Part I: Boron removal in pilot-scale tests", Desalination, 319, 99-106. crossref(new window)

Tu, K.L., Nghiem, L.D. and Chivas, A.R. (2011), "Coupling effects of feed solution pH and ionic strength on the rejection of boron by NF/RO membranes", Chem. Eng. J., 168(2), 700-706. crossref(new window)

USEPA (2006), Edition of the Drinking Water Standards and Health Advisories, Office of Water U.S. Environmental Protection Agency Washington, August 2006.

Van der Bruggen, B., Schaep, J., Wilms, D. and Vandecasteele, C. (1999), "Influence of molecular size, polarity and charge on the retention of organic molecules by nanofiltration", J. Membr. Sci., 156(1), 29-41. crossref(new window)

WHO Guidelines for Drinking Water Quality, Boron (2011), Water Desalination Report, 46(7), February 15, 2010.

Wolska, J. and Bryjak, M. (2013), "Methods for boron removal from aqueous solutions: A review", Desalination, 310, 18-24. crossref(new window)

Yilmaz, A.E., Boncukcuoglu, R. and Kocakerim, M.M. (2007), "A quantitative comparison between electrocoagulation and chemical coagulation for boron removal from boron-containing solution", J. Hazard. Mater., 149(2), 475-481. crossref(new window)

Yoon, J., Amy, G. and Yoon, Y. (2005), "Transport of target anions, chromate, arsenate and perchlorate, through RO, NF and UF membranes", Water Sci. Technol., 51(6-7), 327-334.