Significant Structure of Liquid Methyl Halides

할로겐화 메틸의 액체구조와 성질

  • Lee, Hai-Bang (Department of chemistry, Dong Guk University) ;
  • Chang, Sei-Hun (Department of Chemistry, College of Liberal Arts and Sciences, Seoul National University)
  • Published : 19651200


The partition function of liquid methyl chloride and methyl bromide are developed by applying the significant structure theory of liquid.$^{(1-3)}$ The parameters therein are determined by the modified significant structure theory of liquid.$^{(4)}$ The molar volume, the vapor pressure, and the entropy of vaporization of the liquids are calculated over a wide temperature range. The critical properties for the liquids are also calculated. The results show good agreement with experimental observations.



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