Significant Structure of Liquid Methyl Halides

할로겐화 메틸의 액체구조와 성질

  • Lee, Hai-Bang (Department of chemistry, Dong Guk University) ;
  • Chang, Sei-Hun (Department of Chemistry, College of Liberal Arts and Sciences, Seoul National University)
  • Published : 19651200

Abstract

The partition function of liquid methyl chloride and methyl bromide are developed by applying the significant structure theory of liquid.$^{(1-3)}$ The parameters therein are determined by the modified significant structure theory of liquid.$^{(4)}$ The molar volume, the vapor pressure, and the entropy of vaporization of the liquids are calculated over a wide temperature range. The critical properties for the liquids are also calculated. The results show good agreement with experimental observations.

Keywords

References

  1. Proc. Nat. Acad. Sci. v.44 H. Eyring;Taikyue Ree;N. Hirai
  2. Proc. Nat. Acad. Sci. v.45 E. Jack Fuller;Taikyue Ree;H. Eyring
  3. Proc. Nat. Acad. Sci. v.47 H. Eyring;Taikyue Ree
  4. Journal of the Korean Chemical Society v.8 Seihun Chang(et al.)
  5. J. Am. Chem. Soc. v.62 H. Messerly;J. G. Aston
  6. J. Am. Chem. Soc. v.60 Clark J. Egan;J.D. Kemp
  7. J. Am. Chem. Soc. v.58 Mc. Neight;C.P. Smith
  8. Chem. Ser. No. 29 Adan.
  9. Handbook of Chemistry Lange
  10. Progress in International Research on Thermodynamics and Transport Properties Seihun Chang;Taikyue Ree;H. Eyring;Ingrid Matzner
  11. International Critical Table