Significant Liquid Structure of Binary Mixture, $C_6H_6-C_2H_4Cl_2$

이성분 액체 혼합물의 통계열역학적 연구

  • Ahn, Woon-Sun (College of Liberal Arts and Sciences, Chung Nam University) ;
  • Pak, Hyung-Suk (Department of Chemistry, College of Liberal Arts and Sciences, Seoul National University) ;
  • Chang, Sei-Hun (Department of Chemistry, College of Liberal Arts and Sciences, Seoul National University)
  • Published : 19651200

Abstract

The significant liquid structure theory is extended to binary mixture, benzene-ethylenechloride system. The partition function, applicable throughout the temperature range in which Raoult's law is satisfied is derived. The thermodynamic quantities such as total and partial pressures, molar volumes and mixing entropies are calculated from the partition function at the temperatures $293.15^{\circ},\;323.14^{\circ}\;and\;357.15^{\circ}K.$ The theoretical values, thus calculated, are found to agree with the experimental data in the literatures.

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References

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