The Complexes of Aromatic Amines with Iodine or Iodine Monochloride in Carbon Tetrachloride

방향족아민과 요오드 또는 일염화요오드 사이의 錯物에 관한 연구

  • Choi, Sang-Up (Department of Chemistry, Sogang Jesuit College) ;
  • Lee, Bu-Yong (Department of Chemistry, Sogang Jesuit College)
  • Published : 19670900

Abstract

The systems of aromatic amines such as aniline, N,N-dimethylaniline and N,N-diethylaniline with iodine or iodine monochloride in carbon tetrachloride have been examined spectrophotometrically. The results indicate the formation of one to one molecular complexes. The equilibrium constants obtained at room temperature for formation of the complexes are as follows: $C_6H_5NH_2{\cdot}I_2\;2.05$, $C_6H_5N(CH_3)_2{\cdot}I_2\;15.2$, $C_6H_5N(C_2H_5)_2{\cdot}I_2\;35.5$, $C_6H_5NH_2{\cdot}ICl\;18.5$, $C_6H_5N(CH_3)_2{\cdot}ICl\;25.6$, and $C_6H_5N(C_2H_5)_2\;42.0$ l $mole^{-1}$.

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References

  1. J. Org. Chem. v.26 B.Z. Senkowski;G.S. Panson
  2. J. Am. Chem. Soc. v.82 H. Tsubomura
  3. Trans. Faraday Soc. v.60 A.K. Chandra;D.C. Mukherjee
  4. You Sun Kim
  5. Journal of the Korean Chemical Society v.9 Sang Up Choi;Suck Joo Chang;Shoon Ja Kwon
  6. Journal of the Korean Chemical Society v.9 Sang Up Choi;Bu Yong Lee
  7. J. Chem. Soc. v.1952 D.F. Evans
  8. Journal of the Korean Chemical Society v.11 Sang Up Choi;Eung Ryul Kim