Micelle Catalysis on the Reaction between Triphenylmethane Dyes and Cyanide Ion

Triphenylmethane Dye와 Cyanide Ion과의 반응에 대한 Micelle의 촉매작용

  • Won Fae Koo (Department of Chemistry, Soong Jun University)
  • 구원회 (숭전대학교 문리과대학 화학과)
  • Published : 1973.12.30

Abstract

The reaction between cyanide ion and triphenyl methane dyes is subject to marked catalysis by cationic micelles of cetyltrimethyl ammonium bromide(CTABr) and retarded by anionic micelles of sodium lauryl sulfate(NaLS). Added salts, anions inhibit the catalysis by CTABr, and cations, especially $Zn^{++},\;Cd^{++}$ decrease the retardation of the reaction rates in the presence of NaLS. The kinetic effects of the ionic micelles are much larger in water than in ethanol-water, methanol-water, propanol-water and acetone-water, but strange solvent effects, acceleration the reaction rates, was found in the reaction with malachite green in water-methanol system.

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References

  1. Accounts of Chemical Research v.2 E. H. Cordes;R. Bruce Dunlap
  2. Adv.Phy.Org.Chem. v.8 E. J. Fendler;J. H. Fendler
  3. J. Amer. Chem. Soc. v.81 H. F. Duynstee;E. Grunwald
  4. J. Phys. Chem. v.68 E. W. Anacker;R.M.Rush;J. S. Johnson
  5. Advan. Colloid Iuterface Sci. v.1 P.Mukerjee
  6. J. Amer. Chem. Soc. v.90 C. A. Bunton;E. J. Fendler;L. Sepulvada;K.W.Yang
  7. J. Amer. Chem. Soc. v.90 R.B.Dunlap;E.H.Cordes
  8. J. Phy.Chem. v.73 R. B. Dunlap;E. H. Cordes
  9. J. Amer. Chem. Soc. v.87 M. T. A. Behne;J. G. Fullington;R.Noel;E. H. Cordes
  10. J. Amer. Chem. Soc. v.90 L. R. Ronsted;E. H. Cordes
  11. J.Org.Chem. v.10 M. Poindexter;Bruce Mckay