Complexes of Alkaline Earth Metals with Dibasic Organic Acids in Aqueous, Ethanol-Water and Acetone-Water Solutions

알칼리토류 금속과 2 염기 유기산 사이의 착물

  • 최상업 (서강대학교 이공대학 화학과) ;
  • 이창환 (서강대학교 이공대학 화학과)
  • Published : 1973.12.30


Formation of the complexes of alkaline earth metal ions with malonate and o-phthalate ions in aqueous, ethanol-water and acetone-water solutions (20% by volume) was studied at room temperature by the equilibrium ion exchange technique. This technique involved the measurements of distribution of radioactivity between cation exchange resin(Ion Exchange Resin CGC 241) and solution phases after the radioactive metal ions were equilibriated with the cation exchange resin in the presence of malonate or o-phthalate ions of varying concentrations. The pH of the solutions was controlled to 7.2~7.5, and the ionic strength of the solutions was kept at 0.10~0.11. The results of the present study indicated that the alkaline earth metal ions formed one-to-one complexes with the dibasic organic acids in all solvent systems examined. The present study showed that the relative stabilities of the complexes increased in the order: $Ba^{++}\;<\;Sr^{++}\;<\;Ca^{++}$ complexes. It was also observed that the relative tendency of the o-phthalate ion for the complex formation was somewhat greater than that of malonate ion in each solvent system. Furthermore, it was noted that the complexes were formed more readily in the mixed solvent than in the aqueous solution.



  1. Fundamental Concepts of Inorganic Chemistry E. S. Gilreath
  2. J. Amer. Chem. Soc. v.60 R. K. Cannan;A. Kibrick
  3. J.Amer. Chem. Soc. v.74 J. Schubert;A. Lindenbaum
  4. J. Phys. Chem. v.56 J.Schubert
  5. J.Amer. Chem. Soc. v.76 J. Schubert
  6. J.Amer. Chem. Soc. v.79 N. C. Li;W. M. Westfall;A. Lindenbaum;J. M. White;J. Schubert
  7. This Journal v.16 Sang Up Choi;Hi Chun Kang
  8. This Journal v.14 Sang Up Choi;Young Il Pae;Won Mok Jae
  9. M. S. Thesis, Sogang University Library Chang Whan Rhee