Kinetics and Mechanism of the Hydrolysis of Phenylvinylsulfone

Phenylvinylsulfone의 가수분해 반응메카니즘과 그의 반응속도론적 연구

  • Kim, Tae Rin (Department of Chemistry, College of Science and Engineering, Korea University) ;
  • Choi Choon-Chuel (National Industrial Standards Research Institute)
  • Published : 1975.04.30

Abstract

The rate constants of the hydrolysis of phenylvinylsulfone were determined by ultraviolet spectrophotometry at various pH and a rate equation which can be applied over wide pH range was obtained. The reaction mechanism of hydrolysis of phenylvinylsulfone and especially the catalytic contribution of hydroxide ion which did not study carefully before in acidic media, can be fully explained by the rate equation obtained. The rate equation reveals that: below pH 7, the reaction is initiated by the addition of water molecule to phenylvinylsulfone. At above pH 9, the overall rate constant is only dependent upon the concentration of hydroxide ion.

Keywords

References

  1. The Chemistry of Alkenes S. Patai;Z. Rappoport
  2. Advances in Physical Organic Chemistry v.7 Z. Rappoport
  3. Organic Reactions v.10 E. D. Bergmann
  4. Chem. Rev. v.64 P. Nobler, Jr.;T. G. Borgardt;W. L. Reed
  5. J. Chem. Soc. (B) Y. Ogata;I. Kishi
  6. J. Chem. Soc.(B) W. G. Davies;E. W. Hordisty
  7. J. Chem. Soc.(B) W. G. Davies;E. W. Hardisty
  8. J. Amer. Chem. Soc. v.74 W. E. Truce;E. Wellische
  9. J. Chem. Soc.(B) Shenshav, Z. Rappoport;S. Patai
  10. Tetrahedron v.23 A. Risaliti;S. Fattuta;M. Forchiassin
  11. J. Amer. Chem. Soc. v.83 T. I. Crowell;Francis, Jr.
  12. J. Amer. Chem. Soc. v.95 T. R. Kim;T. I. Crowell
  13. 대한화학회지 v.10 金泰麟;崔永翔
  14. 대한화학회지 v.12 金泰麟;崔永翔
  15. 대한화학회지 v.12 金泰麟;朴玉鉉
  16. Identification of Organic Compounds N. D. Cheronis;J. B. Zntrikin
  17. 고대이공논집 v.8 金泰麟
  18. Fast Reaction K. T. Caldin
  19. Structure and Mechanism in Organic Chemistry C. K. Ingold