A Study on the Tungsten (VI) Complexes with the Organic Acid Anhydrides

유기산 무수물을 리간드로한 텅스텐 (VI) 착물에 관한 연구

  • Sang-Oh Oh (Department of Chemistry, Kyungpook National University) ;
  • Kim, Chan Ho (Busan Custom House Laboratory)
  • Published : 1975.12.30

Abstract

Dichloro-dioxo-tungsten(VI) complexes containing oxygen donor in anhydrous organic acid have been synthesized. Sodium tungstate reacts with acetylchlorides to produce the mononuclear complexes, yellow powder having $WO_2Cl_2(RCO)_2O$ as general formula. Their chemical properties and the possible structure are proposed by the results of spectral data and chemical observation.

Keywords

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