A Study on the Tungsten (VI) Complexes with the Organic Acid Anhydrides

유기산 무수물을 리간드로한 텅스텐 (VI) 착물에 관한 연구

  • Sang-Oh Oh (Department of Chemistry, Kyungpook National University) ;
  • Kim, Chan Ho (Busan Custom House Laboratory)
  • Published : 1975.12.30


Dichloro-dioxo-tungsten(VI) complexes containing oxygen donor in anhydrous organic acid have been synthesized. Sodium tungstate reacts with acetylchlorides to produce the mononuclear complexes, yellow powder having $WO_2Cl_2(RCO)_2O$ as general formula. Their chemical properties and the possible structure are proposed by the results of spectral data and chemical observation.



  1. Inorg. Synthesis M. H. Lietzke;M. L. Holt
  2. Inorg. Chem. v.7 T. M. Brown;E. L. McCann
  3. Inorg. Chem. v.3 R. E. McCarley;T. M. Brown
  4. Inorg. Chem. v.5 S. J. Lippard;B. J. Russ
  5. Inorg. Chem. v.4 O. J. Klejnot
  6. Inorg. Chem. D. P. Rillema;W. J. Reagan;C. H. Brubaker
  7. Inorg. Chem. v.6 T. M. Brown;B. Ruble
  8. Inorg. Chem. v.4 J. S. Yoo;E. Griawold;J. Kleinberg
  9. Inorg. Chem. v.5 M. L. Larson;F. W. Moore
  10. J. Amer. Soc. v.78 H. B. Jonassen;S. Cantor;A. R. Tarssy
  11. J. Korean Chem. Soc. v.18 K. H. Chjo
  12. Angsw. Chem. v.78 J. Selbin
  13. Inorg. Chem. v.4 F. A. Cotton;R. M. Wing
  14. Infrared Spectra of Inerganic and Coordination Compound K. Nakamoto
  15. Low Frequency Vibration of Inorganic and coordination J. R. Ferero
  16. Nipppon Kagaku Kaishi M. Sotani;W. Saito;M. Oita;M. Hasegan
  17. Chem. Ber. v.94 H. L. Krause;W. Huber
  18. Quart. Rev. v.20 P. C. H. Mitchel
  19. Bull. Chem. Soc. Japan v.46 G. Blyholoer;M. Tanake
  20. Russ. Journ., of Inorg. K. N. Mikhalevich;V. N. Litvinchuk
  21. Inorg. Chem. v.1 S. M. Horner;S. Y. Tyree, Jr.