A Synthesis of Tungsten Complexes with Oxine, Aniline or Pyridine in Organic Solvent

有機溶媒中에서 옥신, 아닐린 및 피라딘을 포함하는 텅스텐錯物의 合成

  • Doo Won Park (Department of Chemistry, College of Liberal Arts Science, Kyungpook National University) ;
  • Tae Sub O (Department of Chemistry, Teacher's College, Kyungpook National University)
  • 박두원 (慶北大學校 文理科大學 化學科) ;
  • 오대섭 (慶北大學校 師範大學 化學科)
  • Published : 1975.12.30

Abstract

The insoluble tungsten complexes with 8-hydroxy quinoline (oxine=Hox), aniline (A), and pyridine(Py) in several organic solvents have been synthesized. Using the different solvents with oxine, two different complexes have been synthesized in dichloromethane and dimethylformamide(DMF), respectively. Only one kind of complex has been synthesized with aniline in dichloromethane and with pyridine in acetone. The complexes may be formulated as $WCl_2(Hox)_2,\;[WO_2(Ox_2)],\;[WCl_3A_3],\;and\;[WO_2ClPy]$ by the results of elemental analysis, infrared spectral data, and thermogravimetric analysis.

Keywords

References

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