Determination of Reactivity by MO Theory (VIII). PMO Interpretation for Photocyclodehydrogenation of o-Terphenyl-type compounds

화학반응성의 분자궤도론적 연구 (제8보). o-Terphenyl 형 화합물의 광학적탈수소 고리화 반응에 대한 섭동분자궤도론적 해석

  • Ikchoon Lee (Department of Chemistry, Inha University) ;
  • Bonsu Lee (Department of Chemistry, Inha University)
  • 이익춘 (인하대학교 이과대학 화학과) ;
  • 이본수 (인하대학교 이과대학 화학과)
  • Published : 1976.04.30

Abstract

The photocyclodehydrogenation reaction of o-terphenyl type compounds has been interpreted with perturbational molecular orbital theory. Results show that the mobile bond order for the first excited state is a good reactivity index and this approach is also consistent with the orbital symmetry conservation rule of Woodward and Hoffmann.

Keywords

References

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