Calculation on the NMR Spectrum of trans-2-Butenedial Bishydrazone

trans-2-Butenedial Bishydrazone의 NMR Spectrum에 對한 計算

  • Lee Yong Tae (Department of Chemistry, Youngnam University) ;
  • Lee Hak-ki (Department of Polymer Science, Kyungpook National University)
  • 이용태 (嶺南大學校 文理科大學 化學科) ;
  • 이학기 (慶北大學校 工科大學 高分子工學科)
  • Published : 1977.08.30


The NMR spectrum of newly synthesized compound, trans-2-butenedial bishydrazone is analyzed. It is found that each peak in the AA'BB' spectrum of the compound is consisted of two lines and internal check cannot be accomplished by the usual analytical procedure. Correct line positions are obtained by varying gradually all the parameters, ${\delta}$, K, M, N, L so that the mid points of the doublets may approach observed line positions and the chemical shifts and the coupling constants of the compound are obtained from the result.



  1. J. Korean Chem. Soc. v.13 Hak-ki Lee
  2. J. Amer. Chem. Soc. v.95 Hak-ki Lee;Lynn B. Rodewald
  3. High-resolution Nuclear Magnetic Resonance J. A. Pople;W. G. Schneidera;H. J. Bernstein
  4. Z. Naturforsch v.16a B. Dischler;G. Englert
  5. J. Chem. Phys. v.33 M. Karplus
  6. J. Amer. Chem. Soc. v.84 P. C. Lauterbur ;R. J. Kurland
  7. The Analysis of High Resolution NMR Spectra R. J. Abraham
  8. Structure of High-resolution NMR Spectra P. L. Corio
  9. Can. J. Chem. v.35 J. A. Pople;W. G. Schneider;H. J. Bernstein
  10. J. Chem. Phys. v.38 D. M. Grant;R. C. Hirst
  11. J. Amer. Chem. Soc. v.89 E. Lustig;E. P. Regelis;N. Duy;J. A. Feretti