Journal of the Korean Chemical Society (대한화학회지)

Korean Chemical Society (대한화학회)
권호 표지

The Absolute Rate Measurement by Light Modulation-ESR Technique

Light Modulation-전자상자성공명법을 이용한 절대속도상수의 결정

  • Choo Kwang Yul (Department of Chemistry, Seoul National University) ;
  • Gaspar Peter P. (Department of Chemistry, Seoul National University)
  • 주광열 (서울대학교 자연과학대학 화학과) ;
  • Published : 1977.08.30

Abstract

A rate constant is deduced for the reaction of tert-butoxy radicals and trimethylsilane from the measurement of the phase shift between the modulated light source and the ESR signal of trimethylsilyl radical. The rate constant was found to $3{\times}10^{-2}M^{-1}{\cdot}sec^{-1}$ at $-50^{\circ}C$.

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