Preparation and Reactions of Bis(trimethylsilylmethyl)-1,2-bis(disphenylphosphino)ethanenickel(II)

비스(트리메틸실릴메틸) 1,2-비스(디페닐포스피노)에탄니켈(II)의 합성 및 반응

  • Chong Shik Chin (Department of Chemistry, Sogang University) ;
  • M. D. Curtis (Department of Chemistry, University of Michigan)
  • 진종식 (서강대학교 이공대학 화학과) ;
  • Published : 1981.10.30

Abstract

A new nickel(II) compound, $Ni(CH_2SiMe_3)_2((C_6H_5)_2PCH_2CH_2P(C_6H_5)_2)$, 1, has been prepared by the reaction of $NiCl_2((C_6H_5)_2PCH_2CH_2P(C_6H_5)_2)$ with $Me_3SiCH_2Li$. The compound, 1, is stable under nitrogen at room temperature both in solution and in the solid state. Thermal decomposition of 1 in solution or in the solid produces the reductive coupling product, $Me_3SiCH_2CH_2SiMe_3$ which is also afforded by the reactions of 1 with CO and $O_2$ at room temperature, and with $(C_6H_5)_2PCH_2CH_2P(C_6H_5)_2$ at 80${\circ}$C.

Keywords

References

  1. Advan. Organometal. Chem. v.11 C. S. Cundy;B. M. Kingston;M. F. Lappert
  2. Pure Appl. Chem. v.30 G. Wilkinson
  3. J. Org nometal. Chem. v.57 P. J. Davidson;M. F. Lappert;R. Pearce
  4. J. Chem. Soc., Dalton M. R. Collier;M. F. Lappert;R. Pearce
  5. Chem. Commun. G. Yagupsky;W. Wowat;A. Shortland;G. Wilkinson
  6. Chem. Commun. R. A. Anderson;R. A. Jones;G. Wilkinson
  7. J. Chem. Soc., Dalton R. A. Anderson;R. A. Jones;G. Wilkinson
  8. J. Chem. Soc., Dalton R. A. Anderson;E. Carmona-Guzman;J. F. Gibson;G. Wilkinson
  9. Chem. Commun. E. Carmona-Guzman;G. Wilkinson;J. L. Atwood;R. D. Rogers;M. J. Zawarotko
  10. J. Amer. Chem. Soc. v.100 M. D. Curtis;J. Greene
  11. J. Organometal. Chem. v.25 M. R. Collier;M. F. Lappert;M. M. Truelock
  12. J. Chem. Soc. J. Chatt;F. A. Hart;H. R. Watson
  13. Inorg. Chem. v.2 J. Connolly;G. Urry
  14. The Chemist Companion A. J. Gordon;R. A. Ford
  15. J. Organometal. Chem. v.9 R. J. P. Corriu;J. Masse
  16. J. Amer. Chem. Soc. v.100 T. Yoshida;T. Yamagata;T. H. Tulip;J. Ibers;S. Otsuka
  17. J. Amer. Chem. Soc. v.102 P. Foley;R. DiCosino;G. M. Whitesides
  18. J. Amer. Chem. Soc. v.97 D. G. Morrell;J. K. Kochi
  19. J. Amer. Chem. Soc. v.93 T. Yamamoto;A. Yamamoto;S. Ikeda
  20. Bull. Chem. Soc. Japan v.49 T. Yamamoto;Y. Nakamura;A. Yamamoto
  21. Bull. Chem. Soc. Japan v.49 A. Yamamoto;T. Yamamoto
  22. Progress in Inorganic Chemistry v.24 R. H. Grubbs
  23. J. Amer. Chem. Soc. v.100 R. H. Grubbs;A. Miyashita
  24. J. Chem. Soc. no.A C. K. Brown;D. Georgiou;G. Wilkinson
  25. Inorg. Chem. v.16 M. Wada;K. Kusabe;K. Oguro