Palladium(II) Complexes of Aminophosphines (I). Characterization and Synthesis of $[Pd(L)X_2] with X = Cl^-, Br^-, I^-, NCS^-$

아미노포스핀류를 포함하는 팔라듐 (II) 착물 (제1보). $[Pd(L)X_2] (X = Cl^-, Br^-, I^-, NCS^-)$의 합성과 성질

  • Myung-Ki Doh (Department of Chemistry, Yeungnam University) ;
  • Bong-Gon Kim (Department of Chemistry, Yeungnam University)
  • 도명기 (영남대학교 이과대학 화학과) ;
  • 김봉곤 (영남대학교 이과대학 화학과)
  • Published : 1983.08.20


Several new $[Pd(L)X_2]$ complexes have been prepared with aminophosphines (L) such as trans-1,2-bis[diphenylphosphino)amino]cyclohexane and 1,2-bis[(diphenylphosphino) amino] propane that contain phosphorus atom as ${\pi}$-electron acceptor, and the bond character of complexes have been investigated by means of infrared and electronic spectroscopy. It was found that thiocyanate ions are N-coordinated possibly due to the steric and electronic influence of the phosphorus atom in aminophosphines that formed seven-membered chelate rings, and that spectrochemical series that is derived from the electronic spectra of the complexes is $NCS^- > Cl^- > Br^- > I^-$



  1. Absorption Spectra and Chemical Bonding C. K. Jorgensen
  2. Bull. Chem. Soc. Japan v.54 K. Onuma;A. Nakamura
  3. Inorg. Syn. v.6 J. R. Doyle;P. E. Slade;H. B. Jonassen
  4. J. Chem. Soc., Dalton Trans. J. A. Davies;F. R. Hartley;S. G. Murray
  5. Bull. Chem. Soc. Japan v.48 H. Ogino;J. Fujita
  6. Infrared and Raman Spectra of Inorganic and Coordination Compounds K. Nakamoto
  7. J. Chem. Phys. v.25 L.H. Jones
  8. Infrared and Raman Spectra of Inorganic and Coordination Compounds K. Nakamoto
  9. Nature v.191 A. Turco;C. Pecile
  10. J. Amer. Chem. Soc. v.85 R. G. Pearson
  11. Science v.151 R. G. Pearson
  12. Bull. Chem. Soc. Japan v.55 Y. Otani;Y. Nakamura;S. Kawaguchi;S. Okeya;T. Hinomoto
  13. Inorg. Chem. v.3 J. L. Burmeister;F. Basolo
  14. J. Amer. Chem. Soc. v.92 D. W. Meek;P. E. Nicpon;V. I. Meek
  15. J. Amer. Chem. Soc. v.97 G. J. Palenik;M. Mathew;W. L. Steffen;G. Beran
  16. Inorg. Chem. v.15 W. L. Steffen;G. J. Palenik
  17. Bull, Chem. Soc. Japan v.53 K. Kashiwabara;K. Hanaki;J. Fujita
  18. Spectrochim. Acta v.22 R. A. Chittenden;L. C. Thomas
  19. J. Amer. Chem. Soc. v.92 D. M. Blake;C. J. Nyman
  20. Chem. Lett. (Japan) v.123 R. Saito;Y. Kidani
  21. J. Chem. Soc. J. A. Osborn;F. J. Jardine;J. F. Young;G. Wilkinson
  22. J. Nat. Sci (Yeungnam Univ) v.2 M. K. Doh;B. G. Kim;J. H. Park
  23. Inorg. Syn. v.11 J. M. Jenkins;J. G. Verkade