Oxidative Rearrangement of Tertiary Allylic Alcohols

3차 알릴알코올의 산화전위반응

  • In Kyu Kim (Department of Chemistry, Sung Kyun Kwan University) ;
  • Chang Sok Oh (Department of Chemistry, Sung Kyun Kwan University) ;
  • Young Tech Hong (Department of Chemistry, Sung Kyun Kwan University)
  • 김인규 (성균관대학교 이과대학 화학과) ;
  • 오창석 (성균관대학교 이과대학 화학과) ;
  • 홍영택 (성균관대학교 이과대학 화학과)
  • Published : 1985.08.20

Abstract

A general synthesis of ${\alpha},\{\beta}$-unsaturated carbonyl compounds has been developed by oxidation of t-allylic alcohols. In simpler system, pyridinium chlorochromate oxidation affords the functionality transposed carbonyls in excellent yields, making the reaction a useful and versatile synthetic method

Keywords

References

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