Kinetics on the Reaction of 3,5-Diaryl-1,2,4-dithiazolium Triodide with Hydrazine

삼요오드화 3,5-디아릴-1,2,4-디지아졸륨과 히드라진과의 반응에 관한 반응속도론적 연구

  • Moon-Hwan Park (Department of Chemistry, Hanyang University) ;
  • Chang-Suk Kim (Department of Science Education, Chungbuk National University) ;
  • Soon-Yung Hong (Department of Chemistry, Hanyang University)
  • 박문환 (한양대학교 자연과학대학 화학과) ;
  • 김창석 (충북대학교 사범대학 과학교육과) ;
  • 홍순영 (한양대학교 자연과학대학 화학과)
  • Published : 1985.08.20

Abstract

Pseudo first-order rate constants for reactions of seven m- or p- phenyl-ring substituted 3,5-diphenyl 1,2,4-dithiazolium triodides with hydrazine in excess, in pyridine, were determined by a UV spectrophotometry. For these reactions, calculated some activation parameters, identified the reaction products, and investigated the effect of substituent on the reaction rate. These reactions were accelerated by electron-withdrawing substituents and obeyed the Hammett rule. From the observed kinetics, a reaction mechanism was proposed.

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References

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