Kinetic Studies on Nucleophilic Substitution Reactions of Alkane Sulfonylchlorides with Anilines in MeOH-MeCN Mixtures

메탄올-아세토니트릴 혼합용매에서 염화알칸술포닐과 아닐린의 친핵 치환반응에 대한 속도론적 연구

  • Ikchoon Lee (Department of Chemistry, College of Science, Inha University) ;
  • Han Keun Kang (Department of Chemistry, College of Science, Inha University) ;
  • Hai Whang Lee (Department of Chemistry, College of Science, Inha University)
  • 이익춘 (인하대학교 이과대학 화학과) ;
  • 강한근 (인하대학교 이과대학 화학과) ;
  • 이해황 (인하대학교 이과대학 화학과)
  • Published : 1985.10.20

Abstract

Nucleophilic substitution reactions between Alkanesulfonylchlorides and p-substituted anilines in methanol-acetonitrile mixture have been studied kinetically. Reactivities of substrates, substituent effects of nucleophile and solvent effects indicate that the studied reaction proceeds via $S_N2$. The kinetic results show that transition state of the reaction between i-PSC and anilines becomes looser as the composition of methanol increases.

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References

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