A Study on the Hypersensitive Transitions of Nd(III), Ho(III) and Er(III) Complexes in Aqueous Solution

수용액에서 몇가지 란탄 착화합물의 Hypersensitive Transition에 관한 연구

  • 윤석승 (충남대학교 자연과학대학 화학과) ;
  • 최기영 (목원대학교 화학과) ;
  • 박경균 (한국에너지연구소)
  • Published : 1988.06.20


The hypersensitive $f{\rightarrow}f$ transitions of Nd(III), Ho(III), and Er(III) have been studied for some lanthanide complexes in aqueous solution. Based on the linear correlation between the oscillator strength of the transition and the basicity$(pK_a)$ of the ligand, the covalency in the metal-ligand bonding is discussed for lanthanide anthranilate, pyrazine-2-carboxylate, and pyruvate.



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