A Study for Oxidation Reaction of Alcohols with Cr (Ⅵ)-Isoquinoline Compound (Ⅰ)

Cr (Ⅵ)-Isoquinoline 화합물에 의한 알코올들의 산화반응에 관한 연구 (Ⅰ)

  • 양정성 (경남대학교 화학과) ;
  • 박영조 (경남대학교 이과대학 화학과) ;
  • 백형철 (경남대학교 이과대학 화학과)
  • Published : 19901100

Abstract

Chromium(Ⅵ) compound, [$C_9H_7$NH]$_2Cr_2O_7$ has been prepared by the reaction of isoquinoline with chromium trioxide under the presence of water. [$C_9H_7$NH]$_2Cr_2O_7$ is nonhydroscopic and dissolved in water very well. Structure of [$C_9H_7$NH]$_2Cr_2O_7$ is identified by FTIR spectra and elemental analysis data. The ability of [$C_9H_7$NH]$_2Cr_2O_7$ for the oxidation of alcohols were examined in methylene chloride. [$C_9H_7$NH]$_2Cr_2O_7$ was found as efficient oxidizing agent for the conversion of allyl, primary and secondary alcohols to the corresponding aldehydes or ketones.

Keywords

References

  1. J. Chem. Soc. v.39 Bowden;Heilbron;Jones;Weedon
  2. M. Sc. Thesis, Kyung-Nam University Y. C. Park
  3. Synthesis. Commun. F. S. Jr. Guziec;F. A. Luzzio
  4. J. Org. Chem. v.47 F. S. Jr. Guziec;F. A. Luzzio
  5. The Infra-red Spectra of Complex Molecules V. J. Beilamy
  6. Coord. Chem. Rev. v.6 R. A. Balley;S. L. Kozak;T. W. Michelsem;W. N. Mills
  7. Inorg. Chem. v.6 M. A. Bennett;R. J. H. Clark;A. D. J. Goodwin
  8. Tetrahedron v.18 R. H. Conforth;J. Popjak
  9. Tetrahedron Lett. E. J. Corey;G. W. J. Fleet
  10. Tetrahedron Lett. v.21 T. K. Chakrabrty;S. Chandrasekaran
  11. Heterocycles v.20 H. B. Davis;R. M. Sheets;W. W. Pandler
  12. Heterocycles v.22 H. B. Davis;R. M. Sheets;W. W. Pandler;G. L. Gard
  13. D. Sc. Thesis, Yonsei University S. K. Base
  14. J. Korean Chem. Soc. v.33 J. S. Yang
  15. Tetrahedron Lett. E. J. Corey;J. W. Suggs
  16. Helv. Chem. Acta v.50 H. H. Schmidtke;D. Garthoff