Metal Complexes of Ambidentate Ligand (V). Nickel(II) Complexes of Bis(isonitrosobenzoylacetone)diimine Derivatives

Ambidentate 리간드의 금속착물 (제 5 보). Bis(isonitrosobenzoylacetone)diimine 유도체를 리간드로 하는 니켈(II)착물

  • Jun Young-Sook (Department of Industrial Chemistry, College of Engineering, Kyungpook National University) ;
  • Baek Jae-Bum (Department of Industrial Chemistry, College of Engineering, Kyungpook National University) ;
  • Lee Man-Ho (Department of Industrial Chemistry, College of Engineering, Kyungpook National University)
  • 전영숙 (경북대학교 공과대학 공업화학과) ;
  • 백제범 (경북대학교 공과대학 공업화학과) ;
  • 이만호 (경북대학교 공과대학 공업화학과)
  • Published : 1991.02.20

Abstract

Some nickel(II) complexes have been derived from the condensation of isonitrosobenzoylacetone and diamine(ethylenediamine and propylenediamine) in the presence of metal ion. It is suggested that an isonitroso group(=N-O) of the ligand coordinates to metal through nitrogen atom to form a five-membered ring while other =N-O coordinates to metal through oxygen atom to form a six-membered ring in Ni(IBN)$_2$-en ((IBA)$_2$-en = N,N'-propylenebis(isonitrosobenzoylacetone imino)). But both isonitroso groups of the ligand coordinate to metal through nitrogen atoms to form five-membered rings in Ni(IBA)$_2$-pn ((IBA)$_2$-pn = N,N'-propylenebis(isonitrosobenzoylacetone imino)).

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