Syntheses and Arene Transport Studies of Water Soluble Aminomethylcalixarene

수용성 아미노메틸칼릭스아렌의 합성 및 방향족 물질의 통과실험 연구

  • Kye Chung Nam (Department of Chemistry, Chonnam National University) ;
  • Dae Soon Kim (Department of Chemistry, Chonnam National University)
  • 남계춘 (전남대학교 자연과학대학 화학과) ;
  • 김대순 (전남대학교 자연과학대학 화학과)
  • Published : 1992.12.20


Calix[6]arene react with formaldehyde and secondary amines to yields water soluble Mannich bases which can be converted to the corresponding quaternary salts. Treatment of the quaternary salts with a nucleophile such as cyano, ethoxy, and hydride yields p-substituted calix[6]arenes. Calix[8]arene too react with formaldehyde and diallyl amine to yield a water soluble Mannich base. The transport of neutral arenes through an aqueous phase along a concentration gradient mediated by those of water soluble calixarenes as molecular carrier was studied in a U-type cell. Naphthalene, anthracene, pyrene, and fluoranthene are tested as a neutral solid guest compounds for the transport experiment.



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