Electrochemical Properties of Cu(I)hexafluoroacetylacetonate

Cu(I)hexafluoroacetylacetonate 착화합물들의 전기화학적 성질

  • 최용국 (전남대학교 자연과학대학 화학과) ;
  • 정병구 (전남대학교 자연과학대학 화학과) ;
  • 신현국 (삼성전자주식회사)
  • Published : 1993.09.20

Abstract

Complexes of $Cu(I)(hfac)PR_3$(P: phosphine and R: Me, Et and Bu) as Cu(I)(${\beta}$-diketonate) compounds have been synthesized and their electrochemical properties have been investigated using glassy carbon and carbon microelectrode in aprotic solvent. Reduction process of $Cu(I)(hfac)PR_3$ compounds carried out one electron pathway to Cu(0) by cyclic voltammetry in acetonitrile solution. Chronoamperometric curve using carbon microelectrode shows that these complexes are one electron process and diffusion coefficients are $4.5{\sim}6.7{\times}10^{-6}cm^2$/sec.

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References

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