A Study on the Synthesis of Organophilic Intercalations-complex of [RCOOH]-Montmorillonite and on ItOs Swelling Behavior

양이온교환반응에 의한 Organophilic [RCOOH]-Montmorillonite 층간화합물의 형성과 그 팽윤거동에 관한 연구

  • 김종옥 ;
  • 김택남 ;
  • 조성준
  • Published : 1994.03.01

Abstract

In this research, the organic salt [RCOOH] Br with long alkyl-chain was synthesized, and the organophilic [RCOOH]-Montmorillonite was formed by cation-exchange-reaction between Na-Montmorillonite and synthesized organic salt [RCOOH] Br. After drying of the organophilic [RCOOH]-Montmorillonite at $65^{\circ}C$ in high vaccum, the experiments for the probability of forming its complexes with various swelling-solutions as dist, water, methanol, ethanol, acetonitrile, propionitrile, butyronitrile, toluene and n-decanol were performed, and the corresponding basal spacings obtained were 17.44$\AA$, 31.86$\AA$, 34.38$\AA$, 30.37$\AA$, 32.39$\AA$, 35.04$\AA$, 14.16$\AA$ and 14.63$\AA$ respectively.

Keywords

References

  1. Kolloid-Z.u.Z.Polymere v.243 Anordnung und Orientierung Kationischer Tenside auf Silicatoberfl chen(Ⅳ.Anordnung von n-Alkylammoniumionen bei niedrig geladenen Schichtsilicaten) G.Lagaly;Armin Weiss
  2. 요업학회지 v.5 no.1 Model-system으로서의 몬트모릴로나이트의 층간화합물에 관한 연구(Ⅰ) 조성준;김종옥
  3. Chemie.Physik Verlag IR-Spektroskopie H.G.nzler;H.Bock
  4. Beeinflussung der Sorptionseigenschaften von organophilierten Bentoniten K.Kuhn
  5. Angew.Chemie, Jahrg. Nr.2 Aus der Chemie der hochquellf higen Tone(Bentonite) U.Hofmann
  6. Spektroskopische Methode in der orgn.Chemie H.Messe;H.Meier;B.Zeeh
  7. Angew.Chem. v.75 Organische Derivate der Glimmerartigen Schichtsilicate Armin Weiss
  8. Russian Chemical Reviews v.57 no.2 Layered Silicates as Catalysts M.I.Rozengart;G.M.Vyunova;G.V.Isagulyants
  9. The Aldrich Library of Infrared Spectra(Edition 3), Band 1 C.J.Pouchert
  10. Angew.Chemie.,Nr.30 Rntgenographische und Kolloidchemische Untersuchung ber Ton Ulrich Hofmann;Kurd Endell;Diedrich Wilm
  11. verb.und stark erw.Auft.von Nils Wiberg Lehrbuch der Anorganischen Chemie Holleman.Wiberg
  12. Angew.Chem. v.80 no.18 Aus der Chemie des Tones U.Hofmann
  13. Organikum,2.berichtigter Nachdruck der 15.berar-berteten Auflage
  14. Schr.Angew.Geol.Karlsuhe v.4 K.Kuhn;A.Weiss
  15. Dissertation Studjen uber n-Alkylkomplexe von Montmorilloniten mit 3d-bergangsmetalkationen und uber Katalytische Reaktionen von Oleylalkohol am Montmorilloniten Peter Brunner