The Complex Formation of Gallium Bromide with i-Butyl Bromide in Nitrobenzene)

니트로벤젠용액내에서의 브롬화갈륨과 i-브롬화부틸과의 착물형성에 관한 연구

  • 권오천 (한양대학교 자연과학대학 화학과) ;
  • 남궁진희 (한양대학교 자연과학대학 화학과) ;
  • 최기준 (한양대학교 화학과)
  • Published : 19940300

Abstract

The solubility of i-butyl bromide in nitrobenzene have been measured at 19, 25 and $40^{\circ}C$ in the presence and absence of gallium bromide. In the presence of gallium bromide, 1 : 1 complex, $i-C_4H_9Br{\cdot}GaBr_3$ is formed in the solution. The instability constant K of the complex formation was evaluated from the following equilibrium equation. $i-C_4H_9Br{\cdot}GaBr_3{\rightleftharpoons}C_4H_9Br + 1/2Ga_2Br_6.$ From these result, it seems that the stabilities of the complex formation, gallium bromide with alkyl bromide, are directly related with those of the carbonium ions of alkyl bromide.

Keywords

References

  1. This Journal v.6 Choi, S. U.
  2. This Journal v.15 Kwun, O. C.;Kim, Y. K.
  3. This Journal v.29 Kwun, O. C.;Lee, D. S.;Lee, Y. H.
  4. This Journal v.24 Kwun, O. C.;Kim, Y. C.;Lee, D. S.
  5. J. Phys. Chem. v.34 Johnson, W. C.;Parson, J. B.
  6. Ind. Eng. Chem. v.39 Stull, C. R.
  7. Chem. Revs. v.54 Andrew, L. J.
  8. Electronen Donator-Acceptor Komplexe Briegleb, G.
  9. Rev. Phys. Chem. v.13 Mullinken, R. S.;Person, W. B.
  10. J. Am. Chem. Soc. v.75 Brown, H. C.;Eddy, L. P.;Wong, R.
  11. J. Inorg. Nuclear Chem. v.1 Wong, R.;Brown, H. C.
  12. Organic Chemistry(4th Ed.) Pine, S. H.(et al.)
  13. Gauidebook to Mechanism in Organic Chemistry(4th Ed.) Sykes, P. A.
  14. J. Am. Chem. Soc. v.75 Brown, H. C.;Wallace, W. J.
  15. This Journal v.7 Choi, S. U.