Syntheses and Properties of Polydentate Schiff Base and Their Cu(Ⅱ) Complexes

여러자리 시프 염기 리간드와 구리(Ⅱ) 착물의 합성과 성질

  • 김선덕 (대구대학교 화학과) ;
  • 신윤열 (대구대학교 자연과학대학 화학과) ;
  • 장기호 (대구대학교 화학과)
  • Published : 19940400

Abstract

The novel Schiff base hexadentate ligand, bis-(salicylaldehyde)-triethylentetramine (BSTT) and heptadentate ligand, bis-(salicylaldehyde)-tetraethylenpentamine(BSTP) were synthesized by the reaction of salicylaldehydes with triethylenetetramine and tetraethylenepentamine, having four and five nitrogen atoms, respectively. These liquid Schiff base ligands were become in form of the pale-yellow crystals in the specific pH 4.0 by adding acetic acid concentrated hydrochloric acid. The Cu(Ⅱ) complexes of the Schiff bases were synthesized by reaction of the Schiff base with Cu(Ⅱ) ion and their possible structures were proposed by several analytical data, and physical and chemical properties.

Keywords

References

  1. Inorg. Chem. v.24 Bencini, A.;Benelli, C.;Dei, A.;Gatteschi, D.
  2. J. Am. Chem. Soc. v.100 Sinn, E.;Sim, G.;Dose, E. V.;Tweedle, M. F.;Wilson, L. J.
  3. J. Am. Chem. Soc. v.68 Calvin, M.;Barkeltw, C. H.
  4. J. Am. Chem. Soc. v.68 Hughes, E. W.;Wilmarth, W. K.;Calvin, M.
  5. Chem. Rev. v.63 Vogt Jr., L. H. ;Faigenbaum, H. M.;Wiberley, S. E.
  6. J. Am. Chem. Soc. v.69 Bailes, R. H.;Calvin, M.
  7. Chem. Rev. Niederhoffer, E. C.;Timmons, J. H.;Martell, A. E.
  8. Bull. J. Am. Chem. Soc. v.639 Nakajima, K.;Kojima, K.;Kojima, M.;Fujita, J.
  9. J. Inorg. Nucl. Chem. v.43 Kohli, R. K.;Gopalakreshnan, K.;Bhattacharya, P. K.
  10. J. Am. Chem. Soc. v.82 Holm, R. H.
  11. Inorg. Chim. Acta v.63 Taylor, L. T.;Coleman, W. M.
  12. J. Am. Chem. Soc. v.78 Marvel, C. S.;Aspey, S. A.;Dudley, E. A.
  13. Inorg. Chem. v.24 Giacomelli, A.;Rotunno, T.;Senatore, L.
  14. Inorg. Chem. v.25 Lintvedt, R. L.;Totunno, T.;Senatore, L.
  15. J. Kor. Chem. Soc. v.35 Chjo, K. H.;Choi, Y. K.;Seo, S. S.;Lee, S. J.
  16. J. Inorg. Nucl. Chem. v.41 Nakao, Y.;Mori, W.;Okuda, N.;Nakahara, A.
  17. J. Inorg. Nucl. Chem. v.37 Tayim, H. A.;Ma, A.
  18. J. Inorg. Nucl. Chem. v.42 Shoukry, M. M.;Mahgoub, A. E. S.;Elnagdi, N. H.
  19. J. Kor. Chem. Soc. v.35 Choi, K. S.;Lee, I. H.;Kim, Y. N.
  20. J. Kor. Chem. Soc. v.18 Chjo, K. H.
  21. J. C. S. Dalton. Freyberg, D. P.;Mockler, G. M.;Sinn, E.
  22. Inorg. Chem. v.10 Coleman, W. A.;Taylor, L. T.
  23. Inorg. Chem. v.20 Coleman, W. M.;Boggess, R. K.;Hughes, J. W.;Taylor, L. T.
  24. J. Am. Chem. Soc. v.77 Sarma, B. D.;Bailar Jr., J. C.
  25. J. Am. Chem. Soc. v.72 Jonassen, H. B.;Leblanc, R. B.;Meibohm, A. W.;Rogan, R. M.
  26. Inorg. Chem. v.27 Suh, M. P.;Kang, S. G.
  27. J. Phys. Chem. v.60 Ueno, K.;Martell, A. E.
  28. 日本化學雜誌 v.8 no.11 田中二男
  29. J. Chem. Soc. Hathaway, B. J.;Dudley, R. U.;Nnicholls, P.
  30. J. Chem. Soc. v.94 Hathaway, B. J.;Procter, L. M.;Slad, R. C.;Tomlinson, A. A.
  31. Comprehensive Coordination Chemistry v.2 Calligaris, M.;Randaccio, I.;G. Wilkinson, E. A.
  32. J. Am. Chem. Soc. v.90 Bosnich, B.
  33. J. Inorg. Nucl. Chem. v.44 Coleman, W. M.;Taylor, L. T.
  34. $^{13}C-NMR$ of Natural products v.2 Rahman, A. U.;Ahmad, V. U.
  35. J. Am. Chem. Soc. v.88 Sacconi, L.;Bertini, I.
  36. Inorg. Chem. v.10 Vaira, M. D.;Orioli, P. L.;Sacconi, L.
  37. J. Inorg. Nucl. Chem. v.37 Parikh, P. C.;Patel, D. C.;Bhattacharya, P. K.
  38. J. Am. Chem. Soc. v.86 Sarama, B. D.;Ray, K. R.;Sievers, R. E.;Bailar, J. C.
  39. J. Inorg. Nucl. Chem. v.41 Coleman, W. M.;Taylor, L. T.
  40. J. Kor. Chem. Soc. v.18 Chjo, K. H.;Oh, S. O.;Kim, C. H.
  41. Inorg. Chem. Acta v.131 Naragu, K. K.;Singh, M. K.