A Kinetic Model of the Nonphotochemical Hole Burning : 3-Level System

비광화학적인 홀의 생성에 대한 속도론적 모델 : 유사 3-준위계

  • Lee, In-Ja (Department of Chemistry, Dongguk University)
  • 이인자 (동국대학교 자연과학대학 화학과)
  • Published : 19951000


The theory previously proposed to simulate hole depth in the weak burn intensity limit is extended to examine the hole depth at arbitrary burn intensity using 3-level system model. The hole spectrum simulated using constant fluence gives different hole depth for strong burn intensity while it gives same hole depth for weak burn intensity region. The calculated hole growth curves are compared with published experimental data for oxazine720 in glycerol and tetracene in MTHF glass.



  1. Biochem. Biophys. Acta v.932 Hayes, J. M.;Gillie, J. K.;Tang, D.;Small, G. J.
  2. Chem. Phys. v.101 Carter, T. P.;Fearey, B. L.;Small, G. J.
  3. Chem. Phys. Lett. v.122 Aubert, C.;Funfschilling, J.;Zschokke-Granacher, I.;Siebrand, W.;Wildman, T. A.
  4. Physik. Chem. v.149 Richert, R.;Elschner, A.;Bassler, H. Z.
  5. Chem. Phys. Lett. v.127 Elschner, A.;Richert, R.;Bassler, H.
  6. Opt. Commun. v.12 Kharlamov, B. M.;Personov, R. I.;Bykovskaya, L. A.
  7. Persistent Spectral Hole Burning: Science and Applications Moerner, W. E.(ed.)
  8. Angew. Chem. Int. Ed. Engl. v.23 Friedrich, J.;Haarer, D.
  9. Zero-Phonon lines and Spectral Hole Burning in Spectroscopy and Photochemistry Sild, O.(ed.);Haller, K.(ed.)
  10. Chem. Phys. v.27 Hayes, J. M.;Small, G. J.
  11. J. Chem. Phys. v.90 Jankowiak, R.;Small, G. J.;Athreya, K. B.
  12. Chem. Phys. v.112 Jankowiak, R.;Richer, R.;Bassler, H.
  13. J. Phys. Chem. v.89 Jankowiak, R.;Richert, R.;Bassler, H.
  14. J. Lumin. v.34 Walsh, C. A.;Fayer, M. D.
  15. J. Low Temp. Phys. v.7 Phillips, W. A.
  16. J. Phys. Chem. v.90 Hayes, J. M.;Small, G. J.
  17. Phil. Mag. v.25 Anderson, P. W.;Halperin, B. I.;Varma, C. M.
  18. Chem. Phys. Lett. v.54 Hayes, J. M.;Small, G. J.
  19. J. Lumin. v.36 Jankowiak, R.;Shu, L.;Kenney, M. J.;Small, G. J.
  20. JETP Lett. v.20 Gorokhovskii, V. A. A.;Kaarli, R. K.;Rebane, L. A.
  21. Ph. D. Dissertation (Iowa State Univeristy) Kenney, M. J.