Shock Tube Study on the Reaction of Methyl Radical with Molecular Oxygen

메틸 라디칼과 산소 분자 반응에 관한 충격관 연구

  • 신권수 (숭실대학교 자연과학대학 화학과)
  • Published : 19951000

Abstract

The reaction between $CH_3$ radicals and $O_2$ was investigated in incident shock waves at temperatures between 1390 and 2250 K and densities from 1.5 to 5.3 mol/$m^{+30/3}$ using azomethane as a source of methyl radicals by following the consumption of CH3 radicals with time resolved UV absorption measurements at 213.9 nm. The rate constant expression $k_2=1.35{\times}10^{12}\;exp( - 5900 K/T)\;cm^3 mol^{-1}s^{-1}$ for the reaction of $CH_3 + O_2{\rightarrow}CH_2O + OH$ was derived.

Keywords

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