Synthesis and Characterization of Metal Complex Oxo Vanadium(Ⅳ) Complexes with Derivatives of Salicylaldoximes

옥심계 금속착물의 합성과 그 물성에 관한 연구 치환 살리실알데히드옥심의 바나듐(Ⅳ) 착물(1)

  • Lee, Kwang (Department of Chemistry, Keimyung University) ;
  • Lee, Won Sik (Department of Chemistry, Keimyung University)
  • 이광 (계명대학교 자연과학대학 화학과) ;
  • 이원식 (계명대학교 자연과학대학 화학과)
  • Published : 19950800

Abstract

Oxovanadium(IV) complexes with salicylaldoxime, o-vanilline oxime, 2-hydroxy-4-methoxybenzaldoxime, 2-hydroxy-5-methoxybenzaldoxime and 2-hydroxy-5-nitrobenzaldoxime were synthesized. The complexes have been characterized by elemental analysis, electric conductivity measurement, infrared spectrometry, electronic spectrometry, mass spectrometry, and thermal analysis. The results of elemental analysis were well coincided with the theoretical values. The values of molar conductance of the complexes in DMF implicated that the complexes were non-electrolyte. The characteristic stretching frequency of V=O appeared strong band in the range of $980{\pm}20\;cm^{-1}.$ All the complexes showed two d-d transition in visible spectra and two charge transfer transitions in ultraviolet spectra. Results of mass spectrometry of $VO(sal)_2\;and\;VO(van)_2$ indicated two peaks corresponding to vanadium containing ion(I) of 1 : 2(metal to ligand) chelate and a fragment ion(II) of 1 : 1 chelate due to loss of ligand radical from ion(I). The thermal analysis showed the endothermic peak due to the thermal decomposition.

Keywords

References

  1. Coord. Chem. Rev. v.45 Rice, D. A.
  2. Coord. Chem. Rev. v.78 Colton, R.
  3. Talanta v.26 Singh, R. B.;Garg, B. S.;Singh, R. P.
  4. Inorg. Chim. Acta. v.13 Mehrtra, R. C.;Rai, A. K.;Singh, A.;Bohra, R.
  5. Acta Cryst. v.20 Calleli, M.;Ferraris, G.
  6. Revue Roumaine De Chimie v.20 Biradar, N. S.;Angadi, S. D.
  7. J. Phys. Chem. v.67 Unni, A. K. R.;Elias, L.;Schiff, H. I.
  8. Chemical Applications of Infrared Spectroscopy Rao, C. N. R.
  9. Indian. J. Chem. v.5 Ramaswamy, K. K.;Jose, C. L.;Sen, D. N.
  10. Inorganic Chem. v.1 Ballhausen, C. J.;Gray, H. B.
  11. J. Therm. Analysis. v.25 Lume, P.;Knuuttila, P.
  12. Coord. Chem. Rev. v.13 Chakraborty, A.
  13. J. Phys. Chem. v.59 Sears, P. G.;Wilhot, E. D.;Dawson, S. R.
  14. Comprehendive Coordination Chemistry Bosa, L. V.;Pessoa, J. C.;Sir G. Wilkinson(ed)
  15. Talanta v.4 Henry, J. Hones.;Stone, K. G.
  16. The Chemisty of Titanium and Vanadium Clark, R. J. H
  17. Coord. Chem. Rev. v.37 Rice, D. A.
  18. Anal. Chem. v.32 Pears, G. A.;Pflaum, R. T.
  19. Coord. Chem. Rev. v.1 Nicholis, D.
  20. J. Chem. Rec. v.65 Selbin, J.
  21. Talanta v.19 Egnus, B.
  22. J. Thern. Analysis. v.25 Lume, P.;Knuuttila, P.
  23. Coord. Chem. Rev. v.57 Page, E. M.
  24. Coord. Chem. Rev. v.81 Page, E. M.
  25. Inorg. Chim. Acta. v.171 Cheng, S. H.;Sheen, S. R.;Cheng, C. P.;Chang, C. T.
  26. Coord. Chem. Rev. v.59 Keeney, M. E.;Osso-Assare, K.;Wood, K. A.