Journal of the Korean Chemical Society (대한화학회지)

Korean Chemical Society (대한화학회)
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Reactions of Iron Alkynyl(Ethoxy)Carbene Complexes with Amines

철 알킨일(에톡시)카르벤 착물 유도체와 아민의 반응

  • Park, Jaiwook (Department of Chemistry and Center for Biofunctional Molecules, Pohang University) ;
  • Kim, Jinkyung (Department of Chemistry and Center for Biofunctional Molecules, Pohang University) ;
  • Jung, Hyunmin (Department of Chemistry and Center for Biofunctional Molecules, Pohang University)
  • 박재욱 (포항공과대학교 화학과) ;
  • 김진경 (포항공과대학교 화학과) ;
  • 정현민 (포항공과대학교 화학과)
  • Published : 19960800

Abstract

Iron alkynyl(amino)carbene complexes, (${\beta}$-aminovinyl)carbene complexes, ${\eta}^3$-(2-(alkylcarbonyl)vinyl)carbene complexes, and a 3-aminoallenylidene complex were formed in the reactions of iron alkynyl(ethoxy)carbene complexes with amines. The ratio of the products, which were formed by substitution reaction, the Michael addition of amines, rearrangements after the addition reaction, and the addition followed by the elimination of the ethoxy group, respectively, was dependent on reaction temperature, the substituent of the alkynyl moiety, and employed amines.

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